CINETICA_REACTOR.xlsx
56
7/26/2019 CINETICA_REACTOR.xlsx http://slidepdf.com/reader/full/cineticareactorxlsx 1/56 F(g/h) 130 50 21 10.8 0.05 0.13 0.24 0.35 (Edo estacionario) Determine el orden de reacción y la constante de elocidad h Datos D ! 3.3 cm "ol#ción h ! 80 cm $ ! 1 atm Ec#ación de dise%o &ara #n $F' ! 518 * ! +,1 ! Fl#-o molar del reactio l ! .h !!!! ! π ! π ( 33cm ) 4 4 ! 84.24 ! 0. $ ! Fm !!!! Fn ! Fm $ ! 44 g/ Fn $ F(mol/h) ! 130 g/h !!!! ! 2.,545 mol/h 44 g/mol ! 50 g/h !!!! ! 1.134 mol/h 44 g/mol ! 21 g/h !!!! ! 0.4++3 mol/h 44 g/mol ! 10.8 g/h !!!! ! 0.2455 mol/h 44 g/mol F(g/h) 2.,545 1.134 0.4 "e desea determinar los &arametros cineticos de la reacción de descom&osición En #n reactor t#7#lar ($F') c#ya dimensiones son diametro! 33 cm9 longit#d :#-os a la entrada y es&erando ;#e se alcancen las condiciones estacionarias se datos. < F 0 < * 3 *6 (g) * F 0 Di 2 cm 3 "e as#me ;#e e * 3 *6 es &#ro s n contam nantes9 &or o tanto F n F n F n F n F n F n F n F n PFR / 0 = ∫24_0^ ) (_ ▒ / _ 〖−〗 _
Transcript of CINETICA_REACTOR.xlsx
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 156
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 1 atm
Ecacioacuten de diseo ampara n $F 518 +1
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int24_0^ )(_
_ 〖minus〗 _
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a7la de resltados 005 013 0 lt
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Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 1 atm 1
0081 atmB +115
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int24_1^( 〖1minus 〗 )(1_( )=minusminus int_1^( 〖1minus 〗 )(_ 2 )minus =minusint24_1^(1 minus ) _ 〖 2int24_1^(1 )minus_ 〗
minus2 ) 8( ( + 1minus_1)=minus2 (1 )+(1 )+2 minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1= minus_ _ 2 minus2 ( 1 )minus minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
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4 035
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y m
minus )
08423 B
eaccioacuten y 000314 0003 00223+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
001505 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
+1 )minus
00526 014850
0005001
0015002
0025003
0035004
0045005
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))minus_ +_ ^2 )=rArr 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (_ 1minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
=int_1^(1minus ) _
〖((1+1minus
)^2 ( )minus
)( (int _1^( 〖1minus 〗 ) _ 〖((2 )^2minus )( )(
int_1^( 〖1minus 〗 ) _ 〖(4minus ^24+ ) ( (int_1^( 〖1minus 〗 ) _ 〖( 4 ) )^2( minusint_1( )^2 )( + int_1^(1minus ) _ 〖( ^2 )(
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(minus1)minus4〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 ) +4minus_
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minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
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1
001505
004342 y
0511
gt4
0842
00150
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗 )^2 )=rArr 〗
)^2 )_
)^2 )= minus 〗2 )= 〗 〗
)^2 )= ( 〖1minus 〗 ) _ 〖4 )^2 )=( 〗 〗 〗〗
( 〖1minus 〗 ) _ 〖1038389 + int_1^ minus | 8(1 1)minus_ 〗
+4+1= minus (1minus )+4 _ _ minus4
( 〖907317 0_ 〗 2) 0 =_(1 ) _minus_ minus_ )
020254159860
00001
00002
00003
00004
00005
00006
000000008
7262019 CINETICA_REACTORxlsx
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)=minus (1 ) (14 minus_ +_ minus_ minus_
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m 1
y
minus 0202541 534Egt005
053+23 0000142
B 10215+ 00003408
molB 1534+01 0000+8
minus 0000141 minus 53441Egt005
minus 000034083 minus 000014185
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 ( minus4 (1minus_ )+
053622982 1021959091 1534601259
y
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F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
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035
7262019 CINETICA_REACTORxlsx
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7262019 CINETICA_REACTORxlsx
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F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
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y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
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1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
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)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
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m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
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7262019 CINETICA_REACTORxlsx
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F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
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035
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F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
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)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 256
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 356
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 1 atm 1
0081 atmB +115
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int24_1^( 〖1minus 〗 )(1_( )=minusminus int_1^( 〖1minus 〗 )(_ 2 )minus =minusint24_1^(1 minus ) _ 〖 2int24_1^(1 )minus_ 〗
minus2 ) 8( ( + 1minus_1)=minus2 (1 )+(1 )+2 minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1= minus_ _ 2 minus2 ( 1 )minus minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 456
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 556
y m
minus )
08423 B
eaccioacuten y 000314 0003 00223+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
001505 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
+1 )minus
00526 014850
0005001
0015002
0025003
0035004
0045005
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))minus_ +_ ^2 )=rArr 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (_ 1minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
=int_1^(1minus ) _
〖((1+1minus
)^2 ( )minus
)( (int _1^( 〖1minus 〗 ) _ 〖((2 )^2minus )( )(
int_1^( 〖1minus 〗 ) _ 〖(4minus ^24+ ) ( (int_1^( 〖1minus 〗 ) _ 〖( 4 ) )^2( minusint_1( )^2 )( + int_1^(1minus ) _ 〖( ^2 )(
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(minus1)minus4〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 ) +4minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 656
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 756
1
001505
004342 y
0511
gt4
0842
00150
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗 )^2 )=rArr 〗
)^2 )_
)^2 )= minus 〗2 )= 〗 〗
)^2 )= ( 〖1minus 〗 ) _ 〖4 )^2 )=( 〗 〗 〗〗
( 〖1minus 〗 ) _ 〖1038389 + int_1^ minus | 8(1 1)minus_ 〗
+4+1= minus (1minus )+4 _ _ minus4
( 〖907317 0_ 〗 2) 0 =_(1 ) _minus_ minus_ )
020254159860
00001
00002
00003
00004
00005
00006
000000008
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 856
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 956
m 1
y
minus 0202541 534Egt005
053+23 0000142
B 10215+ 00003408
molB 1534+01 0000+8
minus 0000141 minus 53441Egt005
minus 000034083 minus 000014185
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 ( minus4 (1minus_ )+
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1156
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1356
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 356
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 1 atm 1
0081 atmB +115
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int24_1^( 〖1minus 〗 )(1_( )=minusminus int_1^( 〖1minus 〗 )(_ 2 )minus =minusint24_1^(1 minus ) _ 〖 2int24_1^(1 )minus_ 〗
minus2 ) 8( ( + 1minus_1)=minus2 (1 )+(1 )+2 minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1= minus_ _ 2 minus2 ( 1 )minus minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 456
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 556
y m
minus )
08423 B
eaccioacuten y 000314 0003 00223+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
001505 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
+1 )minus
00526 014850
0005001
0015002
0025003
0035004
0045005
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))minus_ +_ ^2 )=rArr 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (_ 1minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
=int_1^(1minus ) _
〖((1+1minus
)^2 ( )minus
)( (int _1^( 〖1minus 〗 ) _ 〖((2 )^2minus )( )(
int_1^( 〖1minus 〗 ) _ 〖(4minus ^24+ ) ( (int_1^( 〖1minus 〗 ) _ 〖( 4 ) )^2( minusint_1( )^2 )( + int_1^(1minus ) _ 〖( ^2 )(
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(minus1)minus4〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 ) +4minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 656
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 756
1
001505
004342 y
0511
gt4
0842
00150
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗 )^2 )=rArr 〗
)^2 )_
)^2 )= minus 〗2 )= 〗 〗
)^2 )= ( 〖1minus 〗 ) _ 〖4 )^2 )=( 〗 〗 〗〗
( 〖1minus 〗 ) _ 〖1038389 + int_1^ minus | 8(1 1)minus_ 〗
+4+1= minus (1minus )+4 _ _ minus4
( 〖907317 0_ 〗 2) 0 =_(1 ) _minus_ minus_ )
020254159860
00001
00002
00003
00004
00005
00006
000000008
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 856
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 956
m 1
y
minus 0202541 534Egt005
053+23 0000142
B 10215+ 00003408
molB 1534+01 0000+8
minus 0000141 minus 53441Egt005
minus 000034083 minus 000014185
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 ( minus4 (1minus_ )+
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1156
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1356
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 456
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 556
y m
minus )
08423 B
eaccioacuten y 000314 0003 00223+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
001505 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
+1 )minus
00526 014850
0005001
0015002
0025003
0035004
0045005
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))minus_ +_ ^2 )=rArr 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (_ 1minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
=int_1^(1minus ) _
〖((1+1minus
)^2 ( )minus
)( (int _1^( 〖1minus 〗 ) _ 〖((2 )^2minus )( )(
int_1^( 〖1minus 〗 ) _ 〖(4minus ^24+ ) ( (int_1^( 〖1minus 〗 ) _ 〖( 4 ) )^2( minusint_1( )^2 )( + int_1^(1minus ) _ 〖( ^2 )(
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(minus1)minus4〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 ) +4minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 656
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 756
1
001505
004342 y
0511
gt4
0842
00150
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗 )^2 )=rArr 〗
)^2 )_
)^2 )= minus 〗2 )= 〗 〗
)^2 )= ( 〖1minus 〗 ) _ 〖4 )^2 )=( 〗 〗 〗〗
( 〖1minus 〗 ) _ 〖1038389 + int_1^ minus | 8(1 1)minus_ 〗
+4+1= minus (1minus )+4 _ _ minus4
( 〖907317 0_ 〗 2) 0 =_(1 ) _minus_ minus_ )
020254159860
00001
00002
00003
00004
00005
00006
000000008
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 856
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 956
m 1
y
minus 0202541 534Egt005
053+23 0000142
B 10215+ 00003408
molB 1534+01 0000+8
minus 0000141 minus 53441Egt005
minus 000034083 minus 000014185
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 ( minus4 (1minus_ )+
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1156
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1356
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 556
y m
minus )
08423 B
eaccioacuten y 000314 0003 00223+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
001505 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
+1 )minus
00526 014850
0005001
0015002
0025003
0035004
0045005
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))minus_ +_ ^2 )=rArr 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (_ 1minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
=int_1^(1minus ) _
〖((1+1minus
)^2 ( )minus
)( (int _1^( 〖1minus 〗 ) _ 〖((2 )^2minus )( )(
int_1^( 〖1minus 〗 ) _ 〖(4minus ^24+ ) ( (int_1^( 〖1minus 〗 ) _ 〖( 4 ) )^2( minusint_1( )^2 )( + int_1^(1minus ) _ 〖( ^2 )(
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(minus1)minus4〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 ) +4minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 656
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 756
1
001505
004342 y
0511
gt4
0842
00150
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗 )^2 )=rArr 〗
)^2 )_
)^2 )= minus 〗2 )= 〗 〗
)^2 )= ( 〖1minus 〗 ) _ 〖4 )^2 )=( 〗 〗 〗〗
( 〖1minus 〗 ) _ 〖1038389 + int_1^ minus | 8(1 1)minus_ 〗
+4+1= minus (1minus )+4 _ _ minus4
( 〖907317 0_ 〗 2) 0 =_(1 ) _minus_ minus_ )
020254159860
00001
00002
00003
00004
00005
00006
000000008
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 856
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 956
m 1
y
minus 0202541 534Egt005
053+23 0000142
B 10215+ 00003408
molB 1534+01 0000+8
minus 0000141 minus 53441Egt005
minus 000034083 minus 000014185
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 ( minus4 (1minus_ )+
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1156
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1356
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 656
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 756
1
001505
004342 y
0511
gt4
0842
00150
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗 )^2 )=rArr 〗
)^2 )_
)^2 )= minus 〗2 )= 〗 〗
)^2 )= ( 〖1minus 〗 ) _ 〖4 )^2 )=( 〗 〗 〗〗
( 〖1minus 〗 ) _ 〖1038389 + int_1^ minus | 8(1 1)minus_ 〗
+4+1= minus (1minus )+4 _ _ minus4
( 〖907317 0_ 〗 2) 0 =_(1 ) _minus_ minus_ )
020254159860
00001
00002
00003
00004
00005
00006
000000008
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 856
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 956
m 1
y
minus 0202541 534Egt005
053+23 0000142
B 10215+ 00003408
molB 1534+01 0000+8
minus 0000141 minus 53441Egt005
minus 000034083 minus 000014185
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 ( minus4 (1minus_ )+
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1156
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1356
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 756
1
001505
004342 y
0511
gt4
0842
00150
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗 )^2 )=rArr 〗
)^2 )_
)^2 )= minus 〗2 )= 〗 〗
)^2 )= ( 〖1minus 〗 ) _ 〖4 )^2 )=( 〗 〗 〗〗
( 〖1minus 〗 ) _ 〖1038389 + int_1^ minus | 8(1 1)minus_ 〗
+4+1= minus (1minus )+4 _ _ minus4
( 〖907317 0_ 〗 2) 0 =_(1 ) _minus_ minus_ )
020254159860
00001
00002
00003
00004
00005
00006
000000008
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 856
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 956
m 1
y
minus 0202541 534Egt005
053+23 0000142
B 10215+ 00003408
molB 1534+01 0000+8
minus 0000141 minus 53441Egt005
minus 000034083 minus 000014185
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 ( minus4 (1minus_ )+
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1156
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1356
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 856
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 956
m 1
y
minus 0202541 534Egt005
053+23 0000142
B 10215+ 00003408
molB 1534+01 0000+8
minus 0000141 minus 53441Egt005
minus 000034083 minus 000014185
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 ( minus4 (1minus_ )+
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1156
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1356
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 956
m 1
y
minus 0202541 534Egt005
053+23 0000142
B 10215+ 00003408
molB 1534+01 0000+8
minus 0000141 minus 53441Egt005
minus 000034083 minus 000014185
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 ( minus4 (1minus_ )+
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1156
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1356
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1156
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1356
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1156
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1356
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1356
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1356
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1556
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 15 atm
Ecacioacuten de diseo ampara n $F 315 58
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1656
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1756
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 15 atm 1
0081 atmB 58815
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1856
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 1956
y m
minus )
08423 B
eaccioacuten y 000+22 001858 004513+
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003148 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0010020030040050060000800901
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2056
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2156
1
003148
008++5 y
0511
gt4
0842
00314
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2256
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2356
m 1
y
minus 0202541 0000225
053+23 000052
B 10215+ 00014211
molB 1534+01 0002+30+
minus 0000515 minus 00002253+
minus 000142111 minus 00005154
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2556
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2756
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 2956
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 3 atm
Ecacioacuten de diseo ampara n $F +00 +3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3056
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3156
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 3 atm 1
0081 atmB +315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3256
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3356
y m
minus )
08423 B
eaccioacuten y 0008814 00221 00545
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
003805 molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
002
004
006
008
01
012
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3456
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3556
1
003805
0100+5 y
0511
gt4
0842
00380
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
00005
0001
00015
0002
00025
0003
00035
000400045
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3656
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3756
m 1
y
minus 0202541 00003354
053+23 00008+215
B 10215+ 00020+4
molB 1534+01 000403+1
minus 00008+214 minus 0000335458
minus 00020+48+ minus 00008+2145
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3856
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 3956
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4056
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4156
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4356
F(gh) 130 50 21 108
005 013 024 035 (Edo estacionario)
Determine el orden de reaccioacuten y la constante de elocidad
h Datos
D 33 cm
olcioacuten h 80 cm
$ 05 atm
Ecacioacuten de diseo ampara n $F 300 5+3
Fl-o molar del reactio l
h π π ( 33cm )
4 4
8424 0
$ Fm Fn Fm $ 44 g
Fn $
F(molh)
130 gh 2545 molh
44 gmol
50 gh 1134 molh
44 gmol
21 gh 04++3 molh
44 gmol
108 gh 02455 molh
44 gmol
F(gh) 2545 1134 04
e desea determinar los amparametros cineticos de la reaccioacuten de descomamposicioacuten
En n reactor t7lar ($F) cya dimensiones son diametro 33 cm9 longitd-os a la entrada y esamperando e se alcancen las condiciones estacionarias sedatos
lt
F 0
lt
36
(g)
F 0
Di2
cm3
e asme e e 36 es ampro s n contam nantes9 ampor o tanto
F n
F n
F n
F n
F n
F n
F n
F n
PFR
0 =int_0^ )(_ _ 〖minus〗 _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4456
a7la de resltados 005 013 0 lt
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4556
Determinacioacuten de =
gt ( 1
9 n 1 orden de la r
( 1 minus )
( 1 + )
ε moles amprod
a 1 1
1 es ampro
a 1ε 1 1 ε 1 $or lo ta
1
( 1 minus )
( 1 + )
15 = smimos comamportamiento de gas ideal y asA nos eda
imitante 05 atm 1
0081 atmB 5+315
mol=
2 80 cm eordenam
8424 B
ol
1 gt
gtd
y m 1
+3 02455
36 a 518 y 1 atn
80 cm am7iando los7tieron los sigientes
F
F o
F o
lt
F
F o
gtr
n
F
gtr
F
F o
lt
o
ε lt
∆n ∆n
∆n
4 (g)6
(g)
gtr
o
lt
lt
o
$
0
1 gt lt
lt
dlt
0
F 0
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 _
= int_0^ ) (_ 〖10383891103925〗 0_ (_((1 )(1 )) )minus_ +_ 〗
_ 0 ))( ( 0 =1
int_0^ )(1 (_ +_ )_((1 ) )minus_
int_0^ ) (_ 〖(1 ((1 ) )+_ )_ minus_ 〗= int_1^( 〖1minus 〗 )(1+1_( )=minusint_1^(minus 〖1minus 〗 )(2 ) =minusint_1^(1 minus ) _ minus _ 〖 +2int_1^(1 )minus_ 〗
minus2 ) 8(1 1)=minus2 (1 )+(1 )+2 ( + minus_ minus_ minus_(1minus1)minus1
=minus2 (1 )+1minus + (0)minus1=minus2 ( 1 )minus minus_ _ 2 minus_ _
_ 0 ))( ( 0 =1
( (1 )minus )minus minus_ _
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4656
4 035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4756
y m
minus )
08423 B
eaccioacuten y 000244 000485 001543
0052 01485 0308
to minus moles reactantes
minus 1 1
to la ecacioacuten nos eda
0010++ molB
=
o es na reaccioacuten de ampr
s
2
s n amproceso isotCrmico
1 gtlt
0 1 G 1 minus
si 0 G
G
0
lt
F 0
o
smimos e la reaccioacuten es
gtr
lt
1 gtlt
lt
lt
lt
lt
lt
gt2Bn ( 1 gtlt ) gt lt
_ 0 ))( ( 0 =1
int_0^ ) (_ 〖10383891103925〗 _(((1 )(1 )) )minus_ +_
)minus
00526 014850
0005
001
0015
002
0025
003
0035
0 = int_0^ ) (_ 〖1038389 _ 〖minus〗 = int_0^_
((1 )(1 ))^2 )=rArrminus_ +_ 〗 ( 〖907317 0_ 〗int _0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus
int_0^ ) (_ 〖((1 )^2+_ 〖10383891103925〗 )( (1_ minus=int_1^(1 ) minus_ 〖((1+1 )^2 ( ))(minus minus (
) _ 〖((2 )^2 )( )^2 )=minus ( 〗 〗
int_1^( 〖1minus 〗 ) _ 〖(4minus ^2 (4+ ) (int_1^( 〖1minus 〗 ) _ 〖( ) )^2 minusint_14 ( ( )^2 )+ int_1^(1 ) ( minus_ 〖 ^2 )(( (
4int_1^( 〖1minus 〗 ) _ 〖^(minus2) minus4int_1^ int_1^( 〖1minus 〗 ) _ 〖1038389= ( ^(minus1))(4〗 〗 〗
(minus4)(1 ) minus (1minus )minus1+minus_ 4 _ _(1 )minus_ +4
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4856
minus (1minus )+ minus(4+4 )(14 _ _ minus_ minus_)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
+4+1= minus (1minus )+ minus44 _ _
( 〖907317 0_ 〗 2) 0 =_(1 )) _minus_ minus_
020254159860
000005
00001
000015
00002
000025
00003000035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5056
)=minus (1 ) (14 minus_ +_ minus_ minus_
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
y
minus 0202541 283Egt005
053+23 841Egt005
B 10215+ 0000128
molB 1534+01 00003232
minus 841Egt005 minus 2831Egt005
minus 00001284 minus 8401Egt005
2 m 1
1 224401+04452
) lt
lt
1 minus lt
y 1
1
1 (minus4 (1 )+ minus_
053622982 1021959091 1534601259
y
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
F(molh) 2545 1134 04++3 02455
005 013 024 035 lt
005 013 0240
05
1
15
2
25
3
35
XA
F (molh)
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5456
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
035
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 4956
1
0010++
003001+ y
0511
gt4
0842
0010++
mer orden
( 1 minus
( 1 +
1 minus G gt dG m
1
1 minus
m 044
1m
gt2Bn ( 1 gtlt ) gt lt
0
0
2
F 0
Bn (1 gt
0
e 2doorden
gtr
o
2 lt )2
lt )2
lt
dlt
y 2
2
lt
03089 05116
y
) (_ 〖〖10383891103925〗 _ ( 〖907317 0_ 〗 2) 0 =1_ 〗
)^2 )=rArr 〗
)^2 )_ )^2 )= minus int〗 _1^( 〖1minus 〗
)^2 )=( 〖1minus 〗 ) _ 〖 4
)^2 )= 〗 〗 〗〗 〖1minus 〗 ) _ 〖1038389 + 1)minus4 | 8(1 1) minus minus_
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m 1
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7262019 CINETICA_REACTORxlsx
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7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
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7262019 CINETICA_REACTORxlsx
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httpslidepdfcomreaderfullcineticareactorxlsx 5056
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7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
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7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
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7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
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7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5156
m 1
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7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5256
7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
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7262019 CINETICA_REACTORxlsx
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7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5556
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7262019 CINETICA_REACTORxlsx
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7262019 CINETICA_REACTORxlsx
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7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
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7262019 CINETICA_REACTORxlsx
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7262019 CINETICA_REACTORxlsx
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7262019 CINETICA_REACTORxlsx
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7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5356
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7262019 CINETICA_REACTORxlsx
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7262019 CINETICA_REACTORxlsx
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7262019 CINETICA_REACTORxlsx
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7262019 CINETICA_REACTORxlsx
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7262019 CINETICA_REACTORxlsx
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7262019 CINETICA_REACTORxlsx
httpslidepdfcomreaderfullcineticareactorxlsx 5656
7262019 CINETICA_REACTORxlsx
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