高分子学报 2019 年 9 月

第 50 卷 第 9 期

(GAOFENZI XUEBAO)

目 次

专论

医用材料表界面设计及其与细胞相互作用 ············································· 王 蓉 沈新坤 胡 燕 蔡开勇 (863)

酰亚胺基N-型高分子半导体研究进展 ······························································· 史永强 王英锋 郭旭岗 (873)

综述

二次电池用原位生成聚合物电解质的研究进展 ····················································································

········································· 张建军 杨金凤 吴 瀚 张 敏 刘亭亭 张津宁 董杉木 崔光磊 (890)

论文

ABA三嵌段共聚物在油/水乳化液滴中自组装行为的Monte Carlo模拟研究 ·················································

················································································ 郑玲飞 王 铮 尹玉华 蒋 润 李宝会 (915)

基于快速热释放功能的偶氮基光热材料 ···························································· 阎清海 冯奕钰 封 伟 (925)

电诱导自修复纳米复合水凝胶的制备及性能研究 ·················································································

············································ 吴柏燊 叶远超 李 震 刘致远 裴媛媛 陈传瑞 秦海利 刘欢欢 (932)

聚苯乙烯-g-聚(2-乙基-2-噁唑啉)两亲性接枝共聚物的合成与性能 ··············· 窦灿煜 张彦君 张 晨 吴一弦 (939)

聚降冰片烯可逆塑性形状记忆关键影响因素的研究 ············································· 张茂林 季行行 史新妍 (949)

单茂钪催化月桂烯与苯乙烯共聚合的研究 ············································· 刘 薇 宋芸芸 刁凯颖 郭 方 (957)

DNA辅助纳米金三角片的高效纯化与信息编码 ······································ 鲁 爽 方维娜 王丽华 柳华杰 (964)

Acta Polymerica Sinica Vol. 50 No. 9 September 2019

Contents

Feature Articles

Surface/Interface Design of Medical Materials and Their Interactions with Cells ·················································

················································································ Rong Wang, Xin-kun Shen, Yan Hu, Kai-yong Cai (863)

Recent Progress of Imide-functionalized N-type Polymer Semiconductors ························································

··················································································· Yong-qiang Shi, Ying-feng Wang, Xu-gang Guo (873)

Reviews

Research Progress of in situ Generated Polymer Electrolyte for Rechargeable Batteries ·········································

·· Jian-jun Zhang, Jin-feng Yang, Han Wu, Min Zhang, Ting-ting Liu, Jin-ning Zhang, Shan-mu Dong, Guang-lei Cui (890)

Articles

Monte Carlo Simulations of the Self-assembly of ABA Tri-block Copolymers inside an Oil-in-water Emulsion Droplet ····

······························································ Ling-fei Zheng, Zheng Wang, Yu-hua Yin, Run Jiang, Bao-hui Li (915)

Azo-based Photo-thermal Materials Based on Rapid Heat Release ························· Qing-hai Yan, Yi-yu Feng, Wei Feng (925)

Fabrication and Property of Electric-induced Self-healing Nanocomposite Hydrogels ············································

···· Bai-shen Wu, Yuan-chao Ye, Zhen Li, Zhi-yuan Liu, Yuan-yuan Pei, Chuan-rui Chen, Hai-li Qin, Huan-huan Liu (932)

Synthesis and Properties of Polystyrene-g-Poly(2-ethyl-2-oxazoline) Amphiphilic Graft Copolymers ·························

·········································································· Can-yu Dou, Yan-jun Zhang, Chen Zhang, Yi-xian Wu (939)

Study on the Key Factors of Reversible Plasticity Shape Memory of Polynorbornene ············································

························································································· Mao-lin Zhang, Xing-xing Ji, Xin-yan Shi (949)

Copolymerization of Myrcene with Styrene Catalyzed by Half-sandwich Scandium Complexes ································

··············································································· Wei Liu, Yun-yun Song, Kai-ying Diao, Fang Guo (957)

DNA-assisted High-efficient Purifying and Encoding of Gold Nanotriangles ······················································

············································································· Shuang Lu, Wei-na Fang, Li-hua Wang, Hua-jie Liu (964)

《高分子学报》编辑委员会

顾 问： 曹 镛 程正迪 蹇锡高 李永舫 王佛松 吴 奇 杨玉良

张俐娜 周其凤

主 编：张 希

副 主 编：(以下以姓氏汉语拼音为序)

胡文兵 黄 飞 刘冬生 宛新华 王笃金 王献红

委 员：薄志山 陈尔强 陈 红 陈永明 丁建东 傅 强 甘志华

胡 晓 黄飞鹤 黄 维 黄 勇 江东林 江 雷 蒋锡群

李光宪 李 林 李悦生 李志波 李子臣 林嘉平 刘世勇

卢云峰 吕小兵 马於光 乔金樑 史林启 孙俊奇 孙文华

唐本忠 王克智 王利祥 王玉忠 王植源 解孝林 徐志康

杨 柏 杨士勇 杨万泰 杨小牛 杨振忠 余 龙 张 军

张先正 赵 江 郑 强 周永丰 朱美芳

编辑部主任：黄英娟

编辑部成员： 郭舒月 孟令艳 孙一依 赵 华 郑佳之

GAOFENZI XUEBAO （月刊，1957 年创刊）

第 50 卷 第 9 期 2019 年 9 月 20 日

ACTA POLYMERICA SINICA (Monthly, Started in 1957)

Vol. 50 No. 9 September 20, 2019

编 辑 《高分子学报》编委会 Edited by Editorial Board of Acta Polymerica Sinica 地址：北京市海淀区中关村北一街 2 号 Add: Zhongguancun North First Street 2, 邮政编码：100190 Beijing 100190, China 电话：010-62588927 Tel: 010-62588927 http://www.gfzxb.org http://www.gfzxb.org E-mail: gfzxb@iccas.ac.cn E-mail: gfzxb@iccas.ac.cn

主 编 张 希 Editor-in-Chief Xi Zhang 主 管 中国科学院 Administrated by Chinese Academy of Sciences 主 办 中国科学院化学研究所 Sponsored by Institute of Chemistry

中 国 化 学 会 Chinese Academy of Sciences Chinese Chemical Society

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i

Acta Polymerica Sinica Vol. 50 No. 9 September 2019 Cover Image

Research Progress of in situ Generated Polymer Electrolyte for Rechargeable Batteries Jian-jun Zhang, Jin-feng Yang, Han Wu, Min Zhang, Ting-ting Liu, Jin-ning Zhang, Shan-mu Dong, Guang-lei Cui

In situ generated polymer electrolytes can avoid the safety problems caused by liquid electrolytes, and it can also solve the drawbacks in the

prior art of pollution, trivial technological operation and so on at the same time. Furthermore, it can form stable solid/solid interfaces (CEI and

SEI), which are beneficial to improving the cycle life of rechargeable batteries. These advantages give it a promising application prospect.

Acta Polymerica Sinica, 2019, 50(9), 890 − 914

doi: 10.11777/j.issn1000-3304.2019.19097

Acta Polymerica Sinica Vol. 50 No. 9 September 2019 Contents

Feature Articles

Surface/Interface Design of Medical Materials and Their Interactions with Cells Rong Wang, Xin-kun Shen, Yan Hu, Kai-yong Cai

Improving our understanding of the physiological or pathological cell/tissue microenvironment

would greatly benefit the development of better functional surface/interface for biomedical

applications. It’s anticipated that biomaterials with rationally designed surface/interfaces could

regulate the biological properties of cells in the contact region and remodel the surrounding

microenvironment, eventually improving the repairing efficiency of the damaged tissues. Acta Polymerica Sinica, 2019, 50(9), 863 − 872

doi: 10.11777/j.issn1000-3304.2019.19085

Vol. 50, No. 9 ACTA POLYMERICA SINICA 2019

ii

Recent Progress of Imide-functionalized N-type Polymer Semiconductors Yong-qiang Shi, Ying-feng Wang, Xu-gang Guo

This account summarizes the recent progress of N-type polymer semiconductors,

particularly the imide-functionalized polymers, as well as their applications in

high-performance organic field-effect transistors and organic solar cells. Acta Polymerica Sinica, 2019, 50(9), 873 − 889

doi: 10.11777/j.issn1000-3304.2019.19100 Reviews

Research Progress of in situ Generated Polymer Electrolyte for Rechargeable Batteries Jian-jun Zhang, Jin-feng Yang, Han Wu, Min Zhang, Ting-ting Liu, Jin-ning Zhang, Shan-mu Dong, Guang-lei Cui

In situ generation of polymer electrolytes can solve the safety problems displayed by

liquid electrolytes and meanwhile address the issues existing in the prior art such as

pollution, trivial technological operation, etc. Furthermore, it endows the electrolytes

prepared with stable solid/solid interfaces (CEI and SEI), which are beneficial to an

extended cycle life of rechargeable batteries. These advantages make it a promising

technique for practical applications.

Acta Polymerica Sinica, 2019, 50(9), 890 − 914

doi: 10.11777/j.issn1000-3304.2019.19097 Articles

Monte Carlo Simulations of the Self-assembly of ABA Tri-block Copolymers inside an Oil-in-water Emulsion Droplet Ling-fei Zheng, Zheng Wang, Yu-hua Yin, Run Jiang, Bao-hui Li

We investigated the influences of fB and φ on the morphology of ABA tri-block

copolymer particles. The shape of micelles inside a non-porosity particle changes

as fB increased. The successful morphological transition from non-porosity particle

to closed-porosity particle was achieved and then open-porosity particle could be

observed with the increase of φ.

Acta Polymerica Sinica, 2019, 50(9), 915 − 924

doi: 10.11777/j.issn1000-3304.2019.19051

Vol. 50, No. 9 ACTA POLYMERICA SINICA 2019

iii

Azo-based Photo-thermal Materials Based on Rapid Heat Release Qing-hai Yan, Yi-yu Feng, Wei Feng

We introduced a push-pull electronic structure into photo-thermal storage material

of 4-((3,5-dimethoxyaniline)-diazenyl)-2-thiazole/rGO. The fast heat release results

in a high power output, realizing a thermal controllable display. This technology

holds great potential in thermal management system and thermal visualization.

Acta Polymerica Sinica, 2019, 50(9), 925 − 931

doi: 10.11777/j.issn1000-3304.2019.19052

Fabrication and Property of Electric-induced Self-healing Nanocomposite Hydrogels Bai-shen Wu, Yuan-chao Ye, Zhen Li, Zhi-yuan Liu, Yuan-yuan Pei, Chuan-rui Chen, Hai-li Qin, Huan-huan Liu

We prepared a kind of robust and highly stretchable

conductive nanocomposite hydrogel with rapid and

highly efficient self-healing performance.

Combined with the dynamic Au-S coordination

interaction in the polymer network, the damaged

hydrogel can be self-healed in real-time under the

external power supply, providing great potentials as

building blocks for construction of smart, flexible

electronic device.

Acta Polymerica Sinica, 2019, 50(9), 932 − 938

doi: 10.11777/j.issn1000-3304.2019.19047

Synthesis and Properties of Polystyrene-g-Poly(2-ethyl-2-oxazoline) Amphiphilic Graft Copolymers Can-yu Dou, Yan-jun Zhang, Chen Zhang, Yi-xian Wu

Polystyrene-g-poly(2-ethyl-2-oxazoline)

amphiphilic graft copolymers were successfully

synthesized and the above amphiphilic graft

copolymers possess versatile properties such as self-

assembly, emulsification, good thermal stability,

antibacterial property and anti-protein adsorption.

Acta Polymerica Sinica, 2019, 50(9), 939 − 948

doi: 10.11777/j.issn1000-3304.2019.19048

Vol. 50, No. 9 ACTA POLYMERICA SINICA 2019

iv

Study on the Key Factors of Reversible Plasticity Shape Memory of Polynorbornene Mao-lin Zhang, Xing-xing Ji, Xin-yan Shi

The key influence factors affecting reversible plastic shape memory effect of

PNB were studied. Plasticizing oil can adjust Tg to room temperature; PNB has

excellent shape memory performance when the deformation temperature is 2 ℃

lower than Tg initiation temperature and prolonging relaxation time can increase

the shape fixed ratio of PNB.

Acta Polymerica Sinica, 2019, 50(9), 949 − 956

doi: 10.11777/j.issn1000-3304.2019.19050

Copolymerization of Myrcene with Styrene Catalyzed by Half-sandwich Scandium Complexes Wei Liu, Yun-yun Song, Kai-ying Diao, Fang Guo

The copolymerization of myrcene with styrene by the half-sandwich scandium complexes (C5Me4SiMe3)Sc(CH2SiMe3)2(THF) (1) and

(C5H5)Sc(CH2SiMe3)2(THF) (2) have been successfully achieved to afford atactic polystyrene-cis-1,4-polymyrcene diblock copolymers and

syndiotactic polystyrene-3,4-polymyrcene gradient copolymers with controllable compositions, high molecular weight and narrow molecular

weight distribution.

Acta Polymerica Sinica, 2019, 50(9), 957 − 963

doi: 10.11777/j.issn1000-3304.2019.19056

DNA-assisted High-efficient Purifying and Encoding of Gold Nanotriangles Shuang Lu, Wei-na Fang, Li-hua Wang, Hua-jie Liu

We propose a new approach to separate nanoparticles by electrophoresis

according to their sizes and shapes with the help of thiol-DNA. Then such

separated nanoparticles can be linked to other structures through hybridization

of DNA. Therefore, it is a simple and extensible method for purifying raw

product of colloidal nanoparticle.

Acta Polymerica Sinica, 2019, 50(9), 964 − 972

doi: 10.11777/j.issn1000-3304.2019.19049