agust,www,...januar09/Profun-090209ak
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agust,www,...januar09/Profun-090209ak.ppt
description
agust,www,...januar09/Profun-090209ak.ppt. 4). 2). 3). 1). 1) Ed(0), J´= 0 – EVv´=8,J´= 0 = 45.553 cm-1. 2) EVv´=9, J´= 5 – EDv´=0,J´= 5 = 164.24 cm-1. 3) Ef(2), J´= 5 – EVv´=8,J´= 5 = 17.14 cm-1. 4) EVv=10, J´= 3 – Egv=0 J´= 3 = 106.64 cm-1. - PowerPoint PPT Presentation
Transcript of agust,www,...januar09/Profun-090209ak
agust,www,...januar09/Profun-090209ak.ppt
84x103
83
82
81
2 h
[cm
-1]
g3-
(0+),v'=0
V1+
, v'=9
V1+
, v'=10
0
1
1
2
4f3
1(v´=0)
f3
2(v´=0)
f3
3(v´=0)
V1+
, v'=8
V1+
, v'=7
3
C1(v´=1)
D1(v´=0)
F1(v´=0)
d3(v´=0)
d3(v´=0)
g3-
(1),v'=0
E1+
,v'=0
1)
1) Ed(0), J´=0 – EVv´=8,J´=0 = 45.553 cm-1
3)
3) Ef(2), J´=5 – EVv´=8,J´=5 = 17.14 cm-12) EVv´=9, J´=5 – EDv´=0,J´=5 = 164.24 cm-1
2)
4)
4) EVv=10, J´=3 – Egv=0 J´=3 = 106.64 cm-1
agust,heima,...january09/Profun-080209ak.pxp <= agust, heima, ...january09Term values for triplet paper-080209kmak.xls
f3D1 (0)
82544.07
82585.60
82647.27
82729.51
82832.47
82956.54
83100.74
av term
82509.27
82548.29
82606.68
82684.29
82781.5
82896.94
83027.44
DE(f3D1-D1Pi1)
34.8
37.31
40.59
45.22
50.97
59.60
73.30
D1P1(v´=0)
J´
0
1
2
3
4
5
6
7
agust, heima, ...january09/Term values for triplet paper-090209kmak.xls
