agust,www,...januar09/Profun-090209ak.ppt

84x103

83

82

81

2 h

[cm

-1]

g3-

(0+),v'=0

V1+

, v'=9

V1+

, v'=10

0

1

1

2

4f3

1(v´=0)

f3

2(v´=0)

f3

3(v´=0)

V1+

, v'=8

V1+

, v'=7

3

C1(v´=1)

D1(v´=0)

F1(v´=0)

d3(v´=0)

d3(v´=0)

g3-

(1),v'=0

E1+

,v'=0

1)

1) Ed(0), J´=0 – EVv´=8,J´=0 = 45.553 cm-1

3)

3) Ef(2), J´=5 – EVv´=8,J´=5 = 17.14 cm-12) EVv´=9, J´=5 – EDv´=0,J´=5 = 164.24 cm-1

2)

4)

4) EVv=10, J´=3 – Egv=0 J´=3 = 106.64 cm-1

agust,heima,...january09/Profun-080209ak.pxp <= agust, heima, ...january09Term values for triplet paper-080209kmak.xls

f3D1 (0)

82544.07

82585.60

82647.27

82729.51

82832.47

82956.54

83100.74

av term

82509.27

82548.29

82606.68

82684.29

82781.5

82896.94

83027.44

DE(f3D1-D1Pi1)

34.8

37.31

40.59

45.22

50.97

59.60

73.30

D1P1(v´=0)

J´

0

1

2

3

4

5

6

7

agust, heima, ...january09/Term values for triplet paper-090209kmak.xls