The Status of Heavy Metals (Cd, Pb) in the …heavy metals are important pollut-ant in the soils in...

1
GLOBAL SYMPOSIUM ON SOIL POLLUTION 2 - 4 MAY 2018 | FAO - ROME, ITALY The Status of Heavy Metals (Cd, Pb) in the Agricultural Soils of Iran Hamed Rezaei, Saeed Saadat, Karim Shahbazi, Rasoul Mirkhani, Parisa maleki, Leila Esmaeelnejad, Yousefreza Bagheri, Mohammad GhasemZadeh Ganjehie, Alireza Ziaee Javid, Alidad Karami, Homayoun Faghih, Fardin Hamedi, Kamran Azari, Alireza Jafarnejady, Mohammad Tokasi, Tahmineh Bahrampour, Abdolali Shahram, Farrokh Ghani Shayesteh, Javad Ghadbeiklo, Ali Cherati, Mehnoosh Eskandaeri, Faramarz Faeznia, Mohsen Seilsepour, Sara Norouzi, Mahdokht Arjmand, Mohammadhadi Mirzapour, Manochehr Kalhor, Jafar Ali Olad, Ramin Iranipour, Ahmadreza Okhovvatian, Basir Atarodi, Azam Siasar Jahantighi, Alireza Paaknejad, Javad Sarhadi, Abdol Shahrivar, Morteza Pozesh Shirazi, Yaaghoob Hosseini and Zahra Mohammadesmaeil, Mohammad Feizi - Soil and Water Research Institute of Iran INTRODUCTION The pollution of soil is a source of danger to the health of people, ani- mals and crops. The first step in preventing the extension of con- taminated soils is to know the extent and distribution of contam- ination, so they can be accurately programmed based on them. The heavy metals are important pollut- ant in the soils in all over the world. The standard of pollutant levels in agricultural soils with pH higher than 7 is designated 5 and 75 mg.kg -1 for Cd and Pb respective- ly (Iranian Department of Envi- ronment, 2014). METHODOLOGY This study was carried out to study the status of heavy metals in the agricultural soils of Iran using 265 samples distributed in all of coun- try. Samples were chosen based on cropping area and local expert opinion. Soil samples have been taken a depth of 0-30cm and the geographic position was recorded by GPS (Fig. 1). Samples at each point, include at least 5 sub-sam- ples were taken from a circle of 25 m radius to the center of the point, and then a composite sample was prepared. The content of Cd and Pb were measured after passing the samples through 2mm sieve, by the method of Chen and Ma(2001) and using the ICP device. MAIN RESULTS The amount of total soil Cd in dif- ferent region showed that the con- centration of Cd was not more the standard of Iran (5 mg.Kg -1 ). The mean, min and max amount of total soil Cd were 0.29, 0.11 and 0.72 mg.kg -1 , respectively, which implied the risk of Cd pollution, were not observed in studied soils (Table 1 and 2). Total Pb of studied soils was also less than the standard (75mg.Kg -1 ) and its mean amount was 41.4 mg.Kg -1 . Also, the amount of Pb in only 3 soil samples of 265 samples was more than 75 mg.Kg -1 (Fig. 2). CONCLUSION Iran is located in arid and semi arid regions and the extensive range of its soils consists of car- bonated soils. The existence of high amounts of CaCo3 in soils has an important role in fixation and reduction of metals such as Cd and Pb bioavailability. The results of this study demonstrated that pol- lution of Cd and Pb was not signif- icant in studied soils. These results could not show the condition of soil pollution in all regions of Iran. Then, more precise studies must be carried out to determine the polluted lands in Iran. Pollution of soil resources in Iran is not widespread and often is spotted and localized (Fig. 3). By performing surveys with small scale, the probability and possibil- ity of identifying polluted areas is very weak. For this reason the works should be performed on a larger scale. But this requires a lot of time and money. The best way to do this, is identifying high risk areas and determining conducting their boundary, and then studies more precise in of the each areas. max min median mean N Element 0.72 0.11 0.28 0.29 265 Cd 93.92 18.50 39.76 41.36 265 Pb Table 1: Descriptive Statistical analysis of Pb and Cd contents in soil samples. Clay pH OC CaCO3 Element 0.281** -0.276** 0.277** 0.209** Cd -0.160** 0.008 -0.020 -0.486** Pb **. Correlation is significant at the 0.01 level (2-tailed). *. Correlation is significant at the 0.05 level (2-tailed). Table 2: Pearson correlation between Cd and Pb and the other soil characteristics. Fig. 1: soil sampling (a) (b) Fig. 2: Histograms of Cd (a) and Pb (b) amount in soil samples (a) (b) Fig. 3: Distribution of samples and total Cd (a) and Pb (b) in soils

Transcript of The Status of Heavy Metals (Cd, Pb) in the …heavy metals are important pollut-ant in the soils in...

Page 1: The Status of Heavy Metals (Cd, Pb) in the …heavy metals are important pollut-ant in the soils in all over the world. The standard of pollutant levels in agricultural soils with

G L O B A L S Y M P O S I U MO N S O I L

P O L L U T I O N2 - 4 M A Y 2 0 1 8 | F A O - R O M E , I T A L Y

The Status of Heavy Metals (Cd, Pb) in the Agricultural Soils of Iran

Hamed Rezaei, Saeed Saadat, Karim Shahbazi, Rasoul Mirkhani, Parisa maleki, Leila Esmaeelnejad, Yousefreza Bagheri, Mohammad GhasemZadeh Ganjehie, Alireza Ziaee

Javid, Alidad Karami, Homayoun Faghih, Fardin Hamedi, Kamran Azari, Alireza Jafarnejady, Mohammad Tokasi, Tahmineh Bahrampour, Abdolali Shahram, Farrokh Ghani Shayesteh,

Javad Ghadbeiklo, Ali Cherati, Mehnoosh Eskandaeri, Faramarz Faeznia, Mohsen Seilsepour, Sara Norouzi, Mahdokht Arjmand, Mohammadhadi Mirzapour, Manochehr Kalhor, Jafar Ali

Olad, Ramin Iranipour, Ahmadreza Okhovvatian, Basir Atarodi, Azam Siasar Jahantighi, Alireza Paaknejad, Javad Sarhadi, Abdol Shahrivar, Morteza Pozesh Shirazi, Yaaghoob Hosseini and

Zahra Mohammadesmaeil, Mohammad Feizi - Soil and Water Research Institute of Iran

INTRODUCTION

The pollution of soil is a source of danger to the health of people, ani-mals and crops. The first step in preventing the extension of con-taminated soils is to know the extent and distribution of contam-ination, so they can be accurately programmed based on them. The heavy metals are important pollut-ant in the soils in all over the world. The standard of pollutant levels in agricultural soils with pH higher than 7 is designated 5 and 75 mg.kg-1 for Cd and Pb respective-ly (Iranian Department of Envi-ronment, 2014).

METHODOLOGY

This study was carried out to study the status of heavy metals in the agricultural soils of Iran using 265 samples distributed in all of coun-try. Samples were chosen based on cropping area and local expert opinion. Soil samples have been taken a depth of 0-30cm and the geographic position was recorded by GPS (Fig. 1). Samples at each point, include at least 5 sub-sam-ples were taken from a circle of 25 m radius to the center of the point, and then a composite sample was

prepared. The content of Cd and Pb were measured after passing the samples through 2mm sieve, by the method of Chen and Ma(2001) and using the ICP device.

MAIN RESULTS

The amount of total soil Cd in dif-ferent region showed that the con-centration of Cd was not more the standard of Iran (5 mg.Kg-1). The mean, min and max amount of total soil Cd were 0.29, 0.11 and 0.72 mg.kg-1, respectively, which implied the risk of Cd pollution,

were not observed in studied soils (Table 1 and 2). Total Pb of studied soils was also less than the standard (75mg.Kg-1) and its mean amount was 41.4 mg.Kg-1 . Also, the amount of Pb in only 3 soil samples of 265 samples was more than 75 mg.Kg-1 (Fig. 2).

CONCLUSION

Iran is located in arid and semi arid regions and the extensive range of its soils consists of car-bonated soils. The existence of high amounts of CaCo3 in soils has an important role in fixation and reduction of metals such as Cd and Pb bioavailability. The results of this study demonstrated that pol-lution of Cd and Pb was not signif-icant in studied soils. These results could not show the condition of soil pollution in all regions of Iran. Then, more precise studies must be carried out to determine the polluted lands in Iran.Pollution of soil resources in Iran is not widespread and often is spotted and localized (Fig. 3). By performing surveys with small scale, the probability and possibil-ity of identifying polluted areas is very weak. For this reason the works should be performed on a larger scale. But this requires a lot of time and money. The best way to do this, is identifying high risk areas and determining conducting their boundary, and then studies more precise in of the each areas.

Table 1: Descriptive Statistical analysis of Pb and Cd contents in soil samples. maxminmedianmeanNElement

0.720.110.280.29265Cd

93.9218.5039.7641.36265Pb

Table 1: Descriptive Statistical analysis of Pb and Cd contents in soil samples.Table 2: Pearson correlation between Cd and Pb and the other soil characteristics.

ClaypHOCCaCO3Element

0.281**-0.276**0.277**0.209**Cd

-0.160**0.008-0.020-0.486**Pb**. Correlation is significant at the 0.01 level (2-tailed).*. Correlation is significant at the 0.05 level (2-tailed).

Table 2: Pearson correlation between Cd and Pb and the other soil characteristics.

Fig. 1: soil sampling

Fig. 2: Histograms of Cd (a) and Pb (b) amount in soil samples  

(a) (b)

Fig. 2: Histograms of Cd (a) and Pb (b) amount in soil samples

(a) (b)

Fig. 3: Distribution of samples and total Cd (a) and Pb (b) in soils  

Fig. 3:Distribution of samples and total Cd (a) and Pb (b) in soils