80701

= 8.314J trCl mol-l= 6.O22x lf mol-l

= 6.626x lOs J s

=3xlOtms-l

R,VA

hc

{+ qc0U8roc Oq0ad c,erccc qtED.lN+ oOO gdar ogo ge 0E4lr, grdo eO.{+ 6€09 3 gdar06O 8ergft rooonftn.116 0.r!6 odg oOoog tilO.Gg.aGI.a.{e 6.rdrod opocl SoOro d0capsJ Ooa O@o qoao €orrJar.{e 6rtrad ogocl Egt:. Q qr8 gourz$ Cc:oQlj ore8€Od O goOrrJro.* I Ao 50 0l5d ozs oz$ gdarco (r),(2),(,),(4),!5) orn 8p4QOel'J 60Gd€cdg@gd0reoooroil

C*G; c6E a6Ood-m .@c cdoda

odocqioro ogoo Epaq o oracoanJod'dgo 96.'qcroeBo ordq ao odg rog Eqaoqoc ogocf,(1) guardo dq6o6' e) odcaa o€rorrL (3) aeJ oanu.(4) q$gzrJ ooCeDtJoBaJ. (5) oozrj6 ,oU6. \-/

c,lolD q€ aoosjooorrJ oal4our ooulgo gooo oaloal q?CO2, BF3, PF1, CF4, XeFo, SF.

(l) 8og O q€OeO el6o ootcogd OulOar q1rs.(2) 8og O q€OeO soard olOorrl q1o.(3) 8og O q€ qdOrs BEcs qgoOuro oancrsdg.(4) 8og o qq! 86&Eo oO.(5) q€ cq,o', oor6d docoog oo:r odocd rctgo oaod g0grdegJrn go6f oo6.ooro qz$ooa aoocldoocJ ILTPAC rocOo zgOzf q?

2.

(l)(3)(s)

(2) 4-formyl-3-hydroxyhex- l-yne(4) 3-hydroxy4ethyl-t-ynepentahal

(3) NO2F (4) NH3 (s) NHzOH

Ooerdog&o go6f drc68o oquro rod og0ul durrso O

sU6o, T-o1Oo,8-ooC.to$o Soofefcrocd, oroC&a, T-o10o.

5.

(2)(4)

cHoH-C=C-gn-cn-cHrcrl

6n

4-formylhex- I -yn-3-ol2-ethyl-3-hydroxy4ynepentanal2-ethyl-3-hydroxypent-4-ynat

4. i'r8odd:'r8 o.JSrDdG gOcJOcO -l Or,Jerur,(l) Nro4 (2) NzO

OOr od@oqiO OOc $ocar6 (EBdOOcacdq€Oe olOouf 68ood q1o- d0c uro,(l) oUEo, otoC&ro, 8-eoC.(3) oU8o, $ocar8 SdOO*oc4 T-ro1Oo.(5) oBEo, a@o SoaCacrocd, B-oaC.

qlooJEoo ro8oeBo a?e cd{6doocl Q, :o8oddul ocgo, old8da, oqgo oc dg ocdo acq6ut dooC6roogo EooJdroo oo- oo@to 6,dadoocl Q oc Eornecft qlooJSoo iaaeua-2qog Etoocdrno EqorrjEoroqa $O Ocg @Od tcoolcO O€od.(H= 1,N= 14,o= 16, 3oora 6dadoecl Q oc Bourocl Q ocg oBg oars o6ocD eo6 22.4@0.)(1) 33.6 (2) 6i12 (3) 1o0s - (o rs+.+ isl 23s2

I

i

Brws

-2-

AX ao Blt og 69oo8 qgio ooaocs, gron co.c6 c{ro6. acod 6dadoocd Q dococcg gcDracSgoog,"j *rr, ot tr"pr 6o' AX I gcoraoo p oa qod Bx2g oo qoo q oo. oid oad goao og o

(4) a.6 onr ;;(5) orrr oar a614. ococqnrra:J.?*f

tpff.*r*:^:.*._f:? toqord.poo ocaro rodra eQ. oego,oclDcs qooe ogoco vorn qa.s ocda:oa aJronjoo -,,e-eb- ;il;ff;Jii"#l"lt;If"*1,:.3:;$J,X"-:H:::;,f i?: 3.: ?d +. EcsE oi.o oo onrcqrrrac ocso our oqaocdrmdoqc, (r) oc 8o_rnec,

{pl ozoeai 6oE ocrosoo'oarunu ;;:;"ffi;ffi; "Ht#

ourcqalanc ocgoo8 ogelo drorrJoo bo, .qa qz

(3) (n-rylnrPV

7.

9.

;"; """T;:;' '" ft ;& * ;:;: -T :;-"

q?

zdocd ooc zdcc60 .co(t .,ecoo aooaroooa, 'rrJ

zgoa oorrgo go@ oo q?(1) 8og o adocBo T:S "€j, N, ?rgo tooo soe 6dar:fiDod Q g8Soc rod8.

[3] *1?::::::*::.=:--!s::*:--]{;;-d9o6 eoccrooso ooc o1E} o. 1

(3)H,:.&?":.,qo-i.'oJ.6"-,ilil;;-;;E;;;ffi X"%L*jfffi ffit?EIL..oul1l zdocEo cr*q oet to-cq1u gcog o oEloeazdtcBo 906 odo oO-(5) adocd oeito oaopczdcc-aao6-gouoco -racrdoocl-.,Jea-o.a .o.EEoOB (Li) aog6roc aogdog&ooO qlorors to0g urtffiho qco6Co6o,(Li,Z=3 oc ocodzdo odOoqiro dloulOo=f)(l) +3 o toocur o.

{?l .1o ooc qA cr. (3) +3 o ooc 016 o.(4) +7o oOcar o. (5) +Zo o0o qfl o.Q ft8 6d+rrfDoro Q oo0ao qod ocdaoad tge otoo oO4@roacoo oog.

2sO3G) =r 2so2(g) + o2(goo 6dr6doocl Q ocdurc! Eggo qoad.oJg.gag"rr* oro4 rodur eQ. aoeEormooo roloro o€E€Bd ooa6.racoscs8 B0 qooo ooajoaJq;,,,d6,o?_op lg ir".iHr"#; # asoa q?(t) gr8$oco0 oOtgearac gaao (2) o{og"d 6O-goisa(3) cl{o8od *I lortttsocacl (4) o{a8oa qr8 SO3(g 9oa6cr(5) o{oAod ftB O2(g gecsG!

11. asoddrrJ Eodoonj8 o-N-osacoo ooozdooord ooo aqord zg@ 6D oo q?(l) No;' No;' No, , *ol- @\ Noi-, No;, Noz > No;(3) No; r No, r No*, No]- (4) *"_t, *o; , r.r";, .r;(s) No; , No;, uo]- > No,

lll' Gcogod qeor qcog&oocJ 6d roecoocs8 (470 nm) rododoo 6.0J odgozf goqog. oercoocro loxd_?-: BBo toqoc ecogo oacoo.a roc6ozd Rd6o sFD Q? Ess*. -J€'tc

(l) 2.4s @l l.ts (g)'8ss €- r'

(4) 92s (5) loss13' g8socod 298 K oc 10o kPa Eornocl Q-fo1!{o ors qod oo sos 6dadood'q ,; goaocr idocoo8{o erocso' ooo gr66oco .qt -298

K s i oo l00'lckSoaJod E ooa ccgord rgod 56.o qr l

AG AH AS(l) orn o; o,ol?l e5 @d ;;tJ, q6 a6 Oro

10.

(l) dRTP

(4) (ry-q)nPV

(s) l.\-(^r__anlln

,II

I

(2)

-3-

15' droocdoa 6o9 qogo8uJ v,o6ocod drogco@ro gog orJooaal vrogocod rcoo og gEooal t

:B:%1 j*?fj;J?":':T:_T_q?y":iFo,i-.,1s-?9"ueorc,occ,oo.605qos Eaoa soao K. rg. ciocdrdoa scoaecc8 nn_qro-pr-i;;pil;[.""t8]kT',j;3 3'J:aqoul rqo:o grocorao O6lrJ Cr,Cz,%.r Vroqoc SOlOlabardo.ro-6ao4 qf

(r) fi.OffiO.rc(4) *.\fih.rc

S*qqfu"oc-u

1< dtJ- < tO

(3) #'ffi.,0(2\

(s)

16. q.aeuj I aogrgdo ogoozs cs.d ooro gziloour 6rgrrJ ago,f q?

,,,d" ,rd' (3)-,S (4) dt (s)

17.

ffia;ffi fiffiH#:toro 86roco Ro oc ooo sooo ft oo. qc@oro acrrgoo s0% sur qe B(r)k e)i (3)* (o+ (s)+Ifrtr:o "l.lNiG)

oo cuh(aq, l-.0 M)/co(r) quo .lodl', oof6fooodod o6rJ loc co.6 o€r,eo8uJ86oorJ Eqeof do..o8a olbdoccd *16-.- ca. :0g66 "nno ""-5tlo-;r.'[;U;oaco oqrorog Eo ooCdEOOdo€!8 qcdooa oorlcoroo oEo"l,

({r,*^, = -o24v to {oz*/co = + o.s+v)

(l) Ni2*(aq) + Cu(s) --+ Ni(s) + Cu*(aq) ; 0.00 V(2) cu].ta$ + Ni(s) -+ Cu(s) + Nihfaql ; +0.58 V(3) C"].t"et + Ni(s) -.+ Cu(s) + ni2.faql ; -0.58 V(4) cu2*(aq) + Ni(s) --+ Cu(s) * **<rql ; 0.00 V(5) cu(s) + Ni(s) -* cua(aq) + xih(a4l + 4e ; +0.58 v19. acOd 6dadoocl Q toar Ogqo8al ooajoOrdrcl0 Cpr rocalr, oOcsroudrcg0 ccOo g8€oc ad

:ff:iXr':f:j.1i,_tl--T:i:o.e,l-,a'*'.o,.aru*caosocr6..olsooqoceooto€ tottD' 5odm3 oq6 -lcooeort

rro.ea"e l€ozr 4pnr ooc, torffiT'*ir;J:g'ja::L$irr";ff

flT:]fff :?:3"Tfff"*mm"'f ::::.^il;,$;il#;+,esco6ordoooq€ocoaro aoro eQ. qoor Q Narsro, o@co ro00cm3;. "r€

rccoogocJ rocouJ J3]H;f#;;:(ppm o€uI) ogocl, (C = 12, O = iO, o.5 ocoogocl toa*SDo = f.q, * ,o=-a , ;*;(l) too (2) 2So G) soo (4) ?oo (s) looom. acou oo oB aoooco toooaJoso,,l ooa aqozl zgoar oourBca q!E* oulorl q?(l) S og ozd8rod.rn qot$oc _2 go +6 odoaord q.b eoe&ooa.(z) ozd oeozd ogtc Sor66c oqouJ.r*s dio];; s-;s6os rod8.(3) edfk,cdrD.rd too oidgocorsard ora oqqcacdooo soro soc a€ o,ro.(4) Eoc6 grOcaorrlcoui S qorao aOO qO6'",gu"Jqr# .O.(5) acrrlg Hrsono goe qosord, or*a-rdrno; .,J.si;o--..rd osto Soc ros u1ro.

It.

2l' ?T " l^E

nle) +-r rr(8) -r

2 t'IF3@ gr6sooo oqoc aHo = -xi3kJ mor-r oo. N=N oo N-F orrJora Etoorn

i,f*F?rE5fl=:e'r e46ki mor-roc Tt2kt ",ot-t'u.

.-.uri-* ;;- Eoorn orro16f8 qoo(l) -423 (2) -3e3 (3) -l4l (4) t4t (s) 42s

t6n0o6€gO Oodo.

I

I

c'

-5- '

?. Eqed DDodqa oraColf tD€ 89 oa aFf(ao) + 3e+611s) + 6 F-(aq) q6o 96soco rooouJoocsuJ ooraaqoul zgor$ ooo eO q? \-/ Yv3 vu'('ure(l) Al Od8ad.6ca oO.@ AlFl ozd8odrro eO.(3) ru A" Oz*groOa qoddco -3 gO0 qzilOc oo:orJ oO.(4) F-OrJSocdroor$ oga Soc adg.(5) F-od8odrro oO.

cH3cHo oH-,p f ,q (l)cl.{sMgBr,*(2) Ir

goro qdooar g6fioo qEeooog B e oo R g opo ggoOer ogoa,

OH nrrt--- q1(l) CIr3cH2CI{CHo , cH3cH:cHcHo , cH3cH:cu_C, _ottt11

OH(2) cq&ncupno

(1)

OH

(3) cn Jncupno , cH2:cncH2clro , cHr=411-"rr-EH,

OH(4) orEl"rr"ro , crr3crFcucrro , cH3cH-cH-ffL,

OHI(5) Cr{3cr{2orcHo ' CIfcrrdlrcHo ,

GJDccDcEro da6 8l gradcOtfiaar droroo Ddotil,

j#4L#:(T

Qggoloro ro6ao oooar eooo6} qzdoc q1ra. ooo e€goloog ro6co roo!D,,,4Oar OorIEo ar6m oO q?

lll l,,lrtrGrogco tcoe€oocoocJ ooErn T,paddo orod q1a.

:?I l,'lrtr_L-eco aoe€orocoss3 oo8ur T,proddo 6rozd q1ro.

9l lr,l oc Grogco tcO4@orocOoal oOgar T,paddo oazd qia.\1I Sr,L oc G rogco tcO4€raacOecJ oo8ar T,proddo orozd qlo.(5)

',cc., o,i*roO D16 oaazf tc0q@rooc0ocJ oogur T, p add0 4arzdrogoo rcOoora8 gdoo.

gtCHrCH:CH-tuOft

f'-\-, I (3) tcH, crtf -t

crl. H -l

)-( IcH, *f(2)

H HI\/l

f\"1-aOOrrJOsorrJ oors aqoal

P

sr

9H', CH.CH:CHCHO , CH-ell:gtt--,t-Off

C_,,

{j

.l

-7-

n lmOK Q 2No(e)+Brr(8)+ 2NoB($g6$oco oqoc oorB8arsc foroo l25xl0-2mol-rdm3 oo.oOO 6,dadOod Q ooro aqoaf zgour grocoo/gnoco 6ed! oO q?(a) 604€l' ogmoo8 No(g) oc BrJg) gg@o q16 qad qcog g86oco aqoo taoeer$tDc g3orao

S0moldm{oO. ' --(b) aoqetD ogooo8 NoB(g)gr$ao gt6 qrsd gog gs6oco aqoc aoq@oar gorao g0moldm{oo.(c) tcoq@o ograoo8 No(g) oc nrle) sgao qr6 qod qoog g86.rco toqoc aoq6aao 63orao

l2'xl0-2 mol-l dm3 oo.

@ oo4@o fuooro8 NoB(g)egao q(6 q'od qccrE e,E6b',o oqoc ao4@raac Soroo125 x l0-2 mol-l dm3oo.

Xifffjl":"q--9-P-e*6j*.d:ooulooorrlooatoqout4oaoozdao/oozilBaedgoo(a) g66clcoo8 ouzsoroudo:oo 86eeo adrn 6q oere o+s oa3oal ggsoaoula .;;; ffi;(D) gaSoroog cccalg6 qoerctD I :3 oa 6o gr86ocoo8 oozforrcdorso BUrao rodan gq oog 4a oo.(c) od g8Sorooro oculgero qSroo ooc oalaulqaudoroo Eo6 oooorrJ qg oar Eo g6@oceog

EOnocO OO g8$oaoo8 acalgaoog, GJOrs!&! oO.(d) Soro 6dadDoro Q g66oa qo.q ogorag o6oco qg ae Eo gBsora qoo olQo qg Eoo016 oO.

oors aqoul rgoar oozd6o/EloalEl so6d oaurgrl, (eocg8rel) aqoc 6edQ oo q?,

CFo,"oEb.r(a) 8og O ac0al o@oqg OaO rl6ozo gSOg.

(D) 8og O zocOnl acArl, OaJOalo6 Qo O6oauoO rcOo:a sO.(c) €og O rDcad coElAddsl Oul0ra0g Qo O6ouuoO toOcar oO.(d) on*Q C-C-C oaioar 9!or66EJ l2b".rd 60.ocg ga6o' .ooosioooaj ooa Q q6 zgoar oo:rJr8o / o.Drrjr6r aedG oo Q?(a) dg G&DerrOOe qrE o6lotiO OcgooC@o HrSg goOo6(b) NO(e)oEaJ SOr($,SOr(B)ooo o8oBromo Eo 66 adg.G] ooc8g galOro

!r_?.J Q BAoro NO(g) oqg gczootil o6a oaroccl6ozd.@ oqeooceocJ ft8 SO2(g Ce€ oloAo o8rrJ god eo.

qoro 41 8o 50 oraas od 6zd gdrno 6q!oc groco.g5:o arszrr 9Q6oril ad q1a. oo groco gogoo ccdolsoogocl ooro oqoo8 gdooa o6Q (l), (2), (31, r+l io (sj trrr ggocdo@uJ rood g6ocdo g,g oa36rdad opoo8 6,5ra ogo eEeqi todrrJrrr.

fi.

rgABaal oO.tcaa oO.rcroa sO.qarol oO.

6rarg OtD qad, oaron Oan ar$d ogpe8 grocoo gOrdq O oop .s.q6.

OBracOoaJO goraooS C-O OaJOar toUDag oO. O8roc0szilO qcturo tJOcB co0ggadro Ogotgurro tcoggrdro $gOad oO:

HOCH2CH2BT Eop 6rld OcODoc, Q Mg oOog6$oi a6oorrt Surc6 grBracorooi gEsoe roe<}2Dclol'R cC.

oSoQudA@ rocdOod qOoe G,oo(cCo ecOo$arc0 grArocdroo g8$coc oancrodg.

tJ0czoo qzD6O rorQdr oO.

6oa 6,dadood E 2H2(g + CO(g) i* CH.OH(g)rco4@ro Ogaoo8 Eoiro 016 B6oosJ tc'046.

8oo 6,drnd0od Q docoEro oOq@roac0oogqB OcgOo Og6oro EOrao or8 66o{9 Q Oge

t@e6 Eqp asdo.

o€Eq6 trqo6 r9Q6€@m

4;2.

tl3.

I

:r. ..i, itr. r;ra;ii

-8-

45.

fi.

{t.

{E.

49.

50.

{s il+ rls

eoO66oo Oep

I

2

3

4

5

6

7

II roc*doocJ toqioero ,, -ra.rrJoOg-6;J6acrdoocJ oog,o oa Eo qQ0al $Dd og{cadtogoooO Edr{O E6zJoaod 61o6.

qoSro loooccCcocoro gcor:roc0 Og odgar oadgoOo oodzd dqc o0B.

gegrdoeCo8g oroodg qlgtedurOggSgoczor6rtoo ql6fgaro6o ooc {g o.

tocOal loc o8DddrrJ erdOo€i qrld EqAdarfoc0occS qOanto 4Oc gcoc ogcgcrocOalog

EooOoED ocdrrrord e€' fig d6 Ocdo aEoorno Da60 qDO o6odeo8 Ordegcgo eE oO.

tcooaro o{O8oz$ OEul qoooCo.c6o ED€ lDccrccqOO o6odEoS raccrOo g6rrrGo 016 adg.NaOH SdocqrrrocJ Q toc8ra o- croe-.filE

roloraJO agOdo GDc qlorn:rtD zgOdo qoa Od&rooOeoBuJ oOuJ ad q1o.

o06 oofuocl oc8ro Oan qoro Od&cs eO6orotOcorl gD@cd1 OOO 9O ourcoqg.

2.butene oc6$Ocro oOcOoBroocO oorrJ0g. o6oaoa8 qUorr g6EOa r-ro- ogrfrJ2-butene oqrro BEo lorra.

rocOd Cd.adOo€J E MnSG) g dgod gcoaocO pHqoo Ora dqc orocooE

SL(aq) g6ue e0e.- loogdoa odOo oO.

d-eosgo0 e6gO:lD6 gocoro s_oocgo0 pggOlOggOcoroOeO OOc D16 o.

d-oocgo0 gggoaOg ogCoa OaJOur ..g* qot3dccnoo EO toqoc, dao s ooe,rdoa&yr-lr-

IH 2

IIc3

Li4

Be5

B6

c7

NIo

IF

l0Nell

NaL2

Mc13

All4si

l5P

l6s

t7CI

l8Arl9

K20

Ca2lSc

22

fi23

vuCr

25

It[n26

Fe

27

Co28

Ni29

Cu30

7^3lGa

32

Ge33

AE

vSe

35

Br36

KI37

Rb38

Sr39

Y4Zs

42Mo

4tTIb

43

Tc4Ru

45

Rh4Pd

4;t

Atlacd

49Itr

50

Sn5lsb

52

rb53

I54

Xe55

Cs56

BaLa.Lu

72

IIf73

Ih74w

75

Re76

O,s

TT

Ir78

Pt79

AulllUnu

80

_e_tt2Uub

8tTI

82

Pb83

BiuPo

85

Att6Rtr87

FI88

RaAc-Lr

104

Rfl05Db

106

Se

tu7Bh

I(tsEE

I(BMt

110

Uunl13Uut

57Lt

58

Ce59

Pr60

Nd61

Pm62

Sm

63

EuuGd

65

Tb6Dy

67

IIo6E

Er69

Tm70

tr7lLu89

Ac90

Th9lPe

92

U93

Np*tPr

95

Am96

CmnBK

98

CT

99

Es100

tul0lMd

tv2No

103

Lr

u.oePA6ExlEoo rlPAEm