Octavio Manazano Mora

PRES MOLEFRAC TOTAL TOTAL TOTAL WATER TEMP KVL KVL CONVERSION WATER 1-PRO-01atm K C

1 0 370.3455 97.1955 3.206979 0.99999221 0.025 368.9869 95.8369 2.937817 0.95032791 0.05 367.8134 94.6634 2.706934 0.91016041 0.075 366.7993 93.6493 2.507295 0.8777851 0.1 365.9214 92.7714 2.333279 0.85185491 0.125 365.1608 92.0108 2.1805 0.83135291 0.15 364.5016 91.3516 2.045475 0.81549881 0.175 363.9304 90.7804 1.925415 0.8036931 0.2 363.4359 90.2859 1.818064 0.79547581 0.225 363.0084 89.8584 1.721583 0.79049881 0.25 362.6398 89.4898 1.63446 0.78850281 0.275 362.3231 89.1731 1.555444 0.7893031 0.3 362.0521 88.9021 1.483489 0.79277791 0.325 361.8218 88.6718 1.417721 0.79886211 0.35 361.6275 88.4775 1.357398 0.80754151 0.375 361.4655 88.3155 1.301891 0.81885181 0.4 361.3322 88.1822 1.250662 0.8328781 0.425 361.2246 88.0746 1.203251 0.84975751 0.45 361.1402 87.9902 1.159259 0.86968461 0.475 361.0767 87.9267 1.118341 0.89291811 0.5 361.0286 87.8786 1.080053 0.91966661 0.525 361.0018 87.8518 1.04446 0.95063581 0.55 360.9906 87.8406 1.011153 0.98621651 0.575 360.9937 87.8437 0.9799311 1.0270911 0.6 361.0098 87.8598 0.9506198 1.0741241 0.625 361.038 87.888 0.9230662 1.1284251 0.65 361.0776 87.9276 0.8971374 1.1914221 0.675 361.1226 87.9726 0.8725458 1.2647371 0.7 361.181 88.031 0.8494812 1.3512481 0.725 361.2494 88.0994 0.827748 1.4541731 0.75 361.3278 88.1778 0.8072903 1.5782051 0.775 361.4173 88.2673 0.7880792 1.7300561 0.8 361.5196 88.3696 0.7701242 1.9196531 0.825 361.6383 88.4883 0.7534953 2.1623051 0.85 361.7802 88.6302 0.7383687 2.4828831 0.875 361.9591 88.8091 0.7251274 2.9245611 0.9 362.2039 89.0539 0.7146087 3.5692231 0.925 362.5837 89.4337 0.7088045 4.592571 0.95 363.2924 90.1424 0.7133141 6.449141 0.975 365.0579 91.9079 0.7496351 10.768831 1 373.1678 100.0178 0.999997 30.9048

LIQUID LIQUID VAPOR VAPOR LIQUID LIQUIDGAMMA GAMMA MOLEFRAC MOLEFRAC MOLEFRAC MOLEFRACWATER 1-PRO-01 WATER 1-PRO-01 WATER 1-PRO-01

3.54965 1 0 1 0 13.416743 1.00055 0.0734356 0.9265643 0.025 0.9753.286855 1.002233 0.1353474 0.8646526 0.05 0.953.160771 1.005094 0.1880486 0.8119514 0.075 0.9253.039027 1.009181 0.2333303 0.7666697 0.1 0.9

2.92195 1.014546 0.2725659 0.7274341 0.125 0.8752.809708 1.021246 0.3068257 0.6931743 0.15 0.852.702357 1.029348 0.3369529 0.6630471 0.175 0.8252.599864 1.038926 0.3636189 0.6363811 0.2 0.8

2.50214 1.050069 0.3873629 0.6126371 0.225 0.7752.409048 1.062877 0.4086223 0.5913777 0.25 0.752.320429 1.077469 0.4277545 0.5722455 0.275 0.7252.236101 1.093983 0.4450545 0.5549455 0.3 0.72.155874 1.112583 0.460767 0.539233 0.325 0.6752.079554 1.133456 0.4750968 0.5249032 0.35 0.652.006948 1.156826 0.4882163 0.5117837 0.375 0.6251.937864 1.182956 0.5002717 0.4997283 0.4 0.61.872116 1.212157 0.5113879 0.4886121 0.425 0.5751.809527 1.244799 0.521672 0.478328 0.45 0.551.749924 1.281324 0.5312166 0.4687834 0.475 0.5251.693148 1.322269 0.5401315 0.4598685 0.5 0.51.639038 1.368269 0.5484192 0.4515808 0.525 0.4751.587452 1.42012 0.5561827 0.4438173 0.55 0.451.538254 1.478795 0.5634784 0.4365216 0.575 0.4251.491316 1.545509 0.5703573 0.4296427 0.6 0.41.446519 1.621795 0.5768668 0.4231332 0.625 0.3751.403751 1.709615 0.5830517 0.4169483 0.65 0.351.362912 1.811534 0.5889634 0.4110366 0.675 0.3251.323908 1.930901 0.59463 0.40537 0.7 0.31.286654 2.072277 0.6001085 0.3998915 0.725 0.2751.251079 2.24195 0.6054566 0.3945434 0.75 0.251.217121 2.448852 0.6107476 0.3892524 0.775 0.2251.184734 2.706091 0.6160823 0.3839177 0.8 0.21.153891 3.033681 0.6216127 0.3783873 0.825 0.1751.124596 3.46369 0.6275877 0.3724123 0.85 0.151.096896 4.050744 0.6344544 0.3655456 0.875 0.1251.070919 4.895525 0.6431072 0.3568928 0.9 0.11.046951 6.20449 0.6555913 0.3444087 0.925 0.0751.025613 8.470845 0.6775775 0.3224225 0.95 0.051.008421 13.19481 0.7307988 0.2692012 0.975 0.025

1 27.81242 1 0 1 0

0 0.2 0.4 0.6 0.8 1 1.280

85

90

95

100

105

DATOS.PROPANOL.formulaApariencia IncoloroDensidadMasa molarPunto de fusinPunto de ebullicin

sistemaP(atm) 1propanol(compuesto mas volatil) 1agua (compuesto menos volatil) 2

X1 FRACCION MOL DE PROPANOL (LIQUIDO)Y1 FRACCION MOL DE PROPANOL (GAS)X2 FRACCION MOL DE AGUA (LIQUIDO)Y2 FRACCION MOL DE AGUA (GAS)GAMMA 1 COEFICIENTE DE ACTIVIDAD DEL PROPANOLGAMMA 2 COEFICIENTE DE ACTIVIDAD DEL AGUAALFA VOLATILIDAD RELATIVA

CH3-CH2-CH2OH.

790kg/m3; 0,79g/cm360,09g/mol146,7K (-126C)370,3K (97C)

DESTILACION PROPANOL-AGUA

FRACCION MOL DE PROPANOL (LIQUIDO)FRACCION MOL DE PROPANOL (GAS)FRACCION MOL DE AGUA (LIQUIDO)FRACCION MOL DE AGUA (GAS)COEFICIENTE DE ACTIVIDAD DEL PROPANOLCOEFICIENTE DE ACTIVIDAD DEL AGUAVOLATILIDAD RELATIVA

-CH2-CH2OH.

790kg/m3; 0,79g/cm3

146,7K (-126C)370,3K (97C)

CON AYUDA DEL PROGRMA EES CALCULE ALGUNAS PROPIEDADES

CONSTANTES DE ANTOINE

1-Propanol 4.99991 1512.94Agua 5.11564 1687.537

FORMULA.

TEMPERATURPV PROPANOL97.1955 1.0067727195.8369 0.9843839794.6634 0.9652886793.6493 0.9489684192.7714 0.934975692.0108 0.92295491.3516 0.9126112790.7804 0.9037064190.2859 0.8960401189.8584 0.8894445289.4898 0.8837814789.1731 0.878933488.9021 0.8747978188.6718 0.8712926888.4775 0.8683421588.3155 0.8658867788.1822 0.8638695888.0746 0.862243487.9902 0.8609691687.9267 0.8600112187.8786 0.8592860287.8518 0.8588821387.8406 0.8587133787.8437 0.8587600887.8598 0.85900268

87.888 0.8594277187.9276 0.8600247887.9726 0.86070358

88.031 0.86158588.0994 0.86261804

C3H8OH2O

Ref:POLING, BRUCE; PRAUSNITZ, JOHN & O'CONNELL, JOHN."ThePropertiesofGasesandLiquids".5thedition.McGrawHill.NewYork.2001

log10Pvap=A-[B/(TC+C)]bar

88.1778 0.8638030588.2673 0.8651570488.3696 0.8667062788.4883 0.8685059988.6302 0.8706604588.8091 0.8733813389.0539 0.8771128889.4337 0.882921590.1424 0.8938228491.9079 0.92133486

100.0178 1.05424955


205.807230.17

PV AGUA(BAR)0.96149897110.94106383570.92362917030.90872388610.89594093310.8849561983

0.8755035690.86736356620.86035460060.85432368160.84914481340.84471075720.84092798650.83772162350.83502239630.83277602550.83093044730.82944255250.82827662980.82740009830.82673652780.82636694840.82621252780.82625526740.82647725980.82686618070.82741251750.82803362770.8288401236

0.82978534

POLING, BRUCE; PRAUSNITZ, JOHN & O'CONNELL, JOHN."ThePropertiesofGasesandLiquids".5thedition.McGrawHill.NewYork.2001

/(TC+C)]bar

0.83086957140.83210838790.83352578350.83517228830.83714325780.83963227240.84304559610.84835831670.85832725180.88347652261.0048115864

TEMPERATURA PV PROPANOL(BAR) PV AGUA(BAR) X197.1955 1.0067727093 0.9614989711 195.8369 0.9843839673 0.9410638357 0.97594.6634 0.9652886724 0.9236291703 0.9593.6493 0.948968412 0.9087238861 0.92592.7714 0.9349756024 0.8959409331 0.992.0108 0.9229540048 0.8849561983 0.87591.3516 0.9126112747 0.875503569 0.8590.7804 0.9037064117 0.8673635662 0.82590.2859 0.8960401079 0.8603546006 0.889.8584 0.8894445206 0.8543236816 0.77589.4898 0.8837814705 0.8491448134 0.7589.1731 0.8789333959 0.8447107572 0.72588.9021 0.8747978109 0.8409279865 0.788.6718 0.87129268 0.8377216235 0.67588.4775 0.8683421451 0.8350223963 0.6588.3155 0.8658867735 0.8327760255 0.62588.1822 0.8638695828 0.8309304473 0.688.0746 0.8622434002 0.8294425525 0.57587.9902 0.8609691554 0.8282766298 0.5587.9267 0.8600112119 0.8274000983 0.52587.8786 0.8592860228 0.8267365278 0.587.8518 0.8588821296 0.8263669484 0.47587.8406 0.8587133729 0.8262125278 0.4587.8437 0.8587600803 0.8262552674 0.42587.8598 0.8590026826 0.8264772598 0.4

87.888 0.8594277143 0.8268661807 0.37587.9276 0.8600247845 0.8274125175 0.3587.9726 0.8607035813 0.8280336277 0.325

88.031 0.8615849971 0.8288401236 0.388.0994 0.8626180419 0.82978534 0.27588.1778 0.8638030479 0.8308695714 0.2588.2673 0.8651570448 0.8321083879 0.22588.3696 0.8667062739 0.8335257835 0.288.4883 0.8685059876 0.8351722883 0.17588.6302 0.8706604505 0.8371432578 0.1588.8091 0.8733813308 0.8396322724 0.12589.0539 0.8771128826 0.8430455961 0.189.4337 0.8829215008 0.8483583167 0.07590.1424 0.8938228423 0.8583272518 0.0591.9079 0.9213348637 0.8834765226 0.025

100.0178 1.054249551 1.0048115864 0

LIQUID LIQUIDGAMMA GAMMA

X2 suma 1-PRO-01 WATER y1 y20 1 1 3.54965 1 0

0.025 1 1.00055 3.416743 0.91961567 0.080384330.05 1 1.002233 3.286855 0.84820824 0.15179176

0.075 1 1.005094 3.160771 0.78457989 0.215420110.1 1 1.009181 3.039027 0.72772113 0.27227887

0.125 1 1.014546 2.92195 0.67677528 0.323224720.15 1 1.021246 2.809708 0.63101359 0.36898641

0.175 1 1.029348 2.702357 0.58981295 0.410187050.2 1 1.038926 2.599864 0.55263901 0.44736099

0.225 1 1.050069 2.50214 0.51903157 0.480968430.25 1 1.062877 2.409048 0.48859235 0.51140765

0.275 1 1.077469 2.320429 0.46097488 0.539025120.3 1 1.093983 2.236101 0.43588003 0.56411997

0.325 1 1.112583 2.155874 0.41304276 0.586957240.35 1 1.133456 2.079554 0.39223404 0.60776596

0.375 1 1.156826 2.006948 0.37324818 0.626751820.4 1 1.182956 1.937864 0.35590792 0.64409208

0.425 1 1.212157 1.872116 0.34005461 0.659945390.45 1 1.244799 1.809527 0.32554498 0.67445502

0.475 1 1.281324 1.749924 0.31225354 0.687746460.5 1 1.322269 1.693148 0.30010635 0.69989365

0.525 1 1.368269 1.639038 0.28891541 0.711084590.55 1 1.42012 1.587452 0.278635 0.721365

0.575 1 1.478795 1.538254 0.26918048 0.730819520.6 1 1.545509 1.491316 0.26047674 0.73952326

0.625 1 1.621795 1.446519 0.25245147 0.747548530.65 1 1.709615 1.403751 0.24503725 0.75496275

0.675 1 1.811534 1.362912 0.23823755 0.761762450.7 1 1.930901 1.323908 0.23188435 0.76811565

0.725 1 2.072277 1.286654 0.2259562 0.77404380.75 1 2.24195 1.251079 0.2203874 0.7796126

0.775 1 2.448852 1.217121 0.21509814 0.784901860.8 1 2.706091 1.184734 0.20999493 0.79000507

0.825 1 3.033681 1.153891 0.20495033 0.795050670.85 1 3.46369 1.124596 0.19977023 0.80023077

0.875 1 4.050744 1.096896 0.19413538 0.805865620.9 1 4.895525 1.070919 0.18745081 0.81255019

0.925 1 6.20449 1.046951 0.17842563 0.821575370.95 1 8.470845 1.025613 0.16370499 0.83629601

0.975 1 13.19481 1.008421 0.13135763 0.868643371 1 27.81242 1 0 1

APLICACIN DE SOLVER 1/(y1-x1)11 0.29333937 18.0556481 0.29410384 9.82397811 0.29530477 7.121487191 0.29696724 5.804542411 0.29911754 5.044779471 0.30178711 4.566493481 0.30501167 4.251934781 0.30883281 4.042674621 0.31329829 3.906731811 0.31846241 3.82544271 0.32438663 3.787518431 0.33114538 3.786158191 0.3388193 3.817416961 0.34750704 3.879488241 0.35731673 3.972165971 0.36838203 4.096814611 0.38085684 4.256308311 0.39491883 4.455235691 0.4107838 4.700430681 0.4287885 5.002660181 0.44907114 5.373900241 0.47209649 5.835497291 0.49832461 6.417681161 0.52833378 7.167263891 0.562843 8.16003291 0.60277038 9.52718971 0.64954771 11.5257231 0.70440367 14.68091421 0.76959817 20.38993531 0.84806503 33.7694041 0.94393151 100.991131 1.06325865 100.0507111 1.21526293 33.38861841 1.41463287 20.09233041 1.68632251 14.46437431 2.07625248 11.43500011 2.67849493 9.668783161 3.71925554 8.794688651 5.89764866 9.402240471

alfa

PROMEDIO ALFA DESVIACION ESTANDAR

0.85869857 1.0982283

TABLA DE VALORES.

TEMPERATURPV PROPANOLPV AGUA(BARX1 X297.1955 1.00677271 0.96149897 1 095.8369 0.98438397 0.94106384 0.975 0.02594.6634 0.96528867 0.92362917 0.95 0.0593.6493 0.94896841 0.90872389 0.925 0.07592.7714 0.9349756 0.89594093 0.9 0.192.0108 0.922954 0.8849562 0.875 0.12591.3516 0.91261127 0.87550357 0.85 0.1590.7804 0.90370641 0.86736357 0.825 0.17590.2859 0.89604011 0.8603546 0.8 0.289.8584 0.88944452 0.85432368 0.775 0.22589.4898 0.88378147 0.84914481 0.75 0.2589.1731 0.8789334 0.84471076 0.725 0.27588.9021 0.87479781 0.84092799 0.7 0.388.6718 0.87129268 0.83772162 0.675 0.32588.4775 0.86834215 0.8350224 0.65 0.3588.3155 0.86588677 0.83277603 0.625 0.37588.1822 0.86386958 0.83093045 0.6 0.488.0746 0.8622434 0.82944255 0.575 0.42587.9902 0.86096916 0.82827663 0.55 0.4587.9267 0.86001121 0.8274001 0.525 0.47587.8786 0.85928602 0.82673653 0.5 0.587.8518 0.85888213 0.82636695 0.475 0.52587.8406 0.85871337 0.82621253 0.45 0.5587.8437 0.85876008 0.82625527 0.425 0.57587.8598 0.85900268 0.82647726 0.4 0.6

87.888 0.85942771 0.82686618 0.375 0.62587.9276 0.86002478 0.82741252 0.35 0.6587.9726 0.86070358 0.82803363 0.325 0.675

88.031 0.861585 0.82884012 0.3 0.788.0994 0.86261804 0.82978534 0.275 0.72588.1778 0.86380305 0.83086957 0.25 0.7588.2673 0.86515704 0.83210839 0.225 0.77588.3696 0.86670627 0.83352578 0.2 0.8

88.4883 0.86850599 0.83517229 0.175 0.82588.6302 0.87066045 0.83714326 0.15 0.8588.8091 0.87338133 0.83963227 0.125 0.87589.0539 0.87711288 0.8430456 0.1 0.989.4337 0.8829215 0.84835832 0.075 0.92590.1424 0.89382284 0.85832725 0.05 0.9591.9079 0.92133486 0.88347652 0.025 0.975

100.0178 1.05424955 1.00481159 0 1

COEFICIENTE DE VARACION

1.2789450673

LIQUID LIQUIDGAMMA GAMMA

suma 1-PRO-01 WATER y1 y2 APLICACIN 1 1 3.54965 1 0 11 1.00055 3.416743 0.91961567 0.08038433 11 1.002233 3.286855 0.84820824 0.15179176 11 1.005094 3.160771 0.78457989 0.21542011 11 1.009181 3.039027 0.72772113 0.27227887 11 1.014546 2.92195 0.67677528 0.32322472 11 1.021246 2.809708 0.63101359 0.36898641 11 1.029348 2.702357 0.58981295 0.41018705 11 1.038926 2.599864 0.55263901 0.44736099 11 1.050069 2.50214 0.51903157 0.48096843 11 1.062877 2.409048 0.48859235 0.51140765 11 1.077469 2.320429 0.46097488 0.53902512 11 1.093983 2.236101 0.43588003 0.56411997 11 1.112583 2.155874 0.41304276 0.58695724 11 1.133456 2.079554 0.39223404 0.60776596 11 1.156826 2.006948 0.37324818 0.62675182 11 1.182956 1.937864 0.35590792 0.64409208 11 1.212157 1.872116 0.34005461 0.65994539 11 1.244799 1.809527 0.32554498 0.67445502 11 1.281324 1.749924 0.31225354 0.68774646 11 1.322269 1.693148 0.30010635 0.69989365 11 1.368269 1.639038 0.28891541 0.71108459 11 1.42012 1.587452 0.278635 0.721365 11 1.478795 1.538254 0.26918048 0.73081952 11 1.545509 1.491316 0.26047674 0.73952326 11 1.621795 1.446519 0.25245147 0.74754853 11 1.709615 1.403751 0.24503725 0.75496275 11 1.811534 1.362912 0.23823755 0.76176245 11 1.930901 1.323908 0.23188435 0.76811565 11 2.072277 1.286654 0.2259562 0.7740438 11 2.24195 1.251079 0.2203874 0.7796126 11 2.448852 1.217121 0.21509814 0.78490186 11 2.706091 1.184734 0.20999493 0.79000507 1

1 3.033681 1.153891 0.20495033 0.79505067 11 3.46369 1.124596 0.19977023 0.80023077 11 4.050744 1.096896 0.19413538 0.80586562 11 4.895525 1.070919 0.18745081 0.81255019 11 6.20449 1.046951 0.17842563 0.82157537 11 8.470845 1.025613 0.16370499 0.83629601 11 13.19481 1.008421 0.13135763 0.86864337 11 27.81242 1 0 1 1

1/(y1-x1) |

0.29333937 18.0556480.29410384 9.82397810.29530477 7.121487190.29696724 5.804542410.29911754 5.044779470.30178711 4.566493480.30501167 4.251934780.30883281 4.042674620.31329829 3.906731810.31846241 3.82544270.32438663 3.787518430.33114538 3.78615819

0.3388193 3.817416960.34750704 3.879488240.35731673 3.972165970.36838203 4.096814610.38085684 4.256308310.39491883 4.45523569

0.4107838 4.700430680.4287885 5.00266018

0.44907114 5.373900240.47209649 5.835497290.49832461 6.417681160.52833378 7.16726389

0.562843 8.16003290.60277038 9.52718970.64954771 11.5257230.70440367 14.68091420.76959817 20.38993530.84806503 33.7694040.94393151 100.991131.06325865 100.050711

alfa

1.21526293 33.38861841.41463287 20.09233041.68632251 14.46437432.07625248 11.43500012.67849493 9.668783163.71925554 8.794688655.89764866 9.40224047

33.4892442

TEMPERATURA X1 y197.1955 1 195.8369 0.975 0.9196156794.6634 0.95 0.8482082493.6493 0.925 0.7845798992.7714 0.9 0.7277211392.0108 0.875 0.6767752891.3516 0.85 0.6310135990.7804 0.825 0.5898129590.2859 0.8 0.5526390189.8584 0.775 0.5190315789.4898 0.75 0.4885923589.1731 0.725 0.4609748888.9021 0.7 0.4358800388.6718 0.675 0.4130427688.4775 0.65 0.3922340488.3155 0.625 0.3732481888.1822 0.6 0.3559079288.0746 0.575 0.3400546187.9902 0.55 0.3255449887.9267 0.525 0.3122535487.8786 0.5 0.3001063587.8518 0.475 0.2889154187.8406 0.45 0.27863587.8437 0.425 0.2691804887.8598 0.4 0.26047674

87.888 0.375 0.2524514787.9276 0.35 0.2450372587.9726 0.325 0.23823755

88.031 0.3 0.2318843588.0994 0.275 0.225956288.1778 0.25 0.220387488.2673 0.225 0.2150981488.3696 0.2 0.2099949388.4883 0.175 0.2049503388.6302 0.15 0.1997702388.8091 0.125 0.1941353889.0539 0.1 0.1874508189.4337 0.075 0.1784256390.1424 0.05 0.1637049991.9079 0.025 0.13135763

0 0.2 0.4 0.6 0.8 1 1.280

85

90

95

100

105

100.0178 0 0

0 0.2 0.4 0.6 0.8 1 1.280

85

90

95

100

105

X1 1/(y1-x1)1

0.975 18.0556480.95 9.8239781

0.925 7.121487190.9 5.80454241

0.875 5.044779470.85 4.56649348

0.825 4.251934780.8 4.04267462

0.775 3.906731810.75 3.8254427

0.725 3.787518430.7 3.78615819

0.675 3.817416960.65 3.87948824

0.625 3.972165970.6 4.09681461

0.575 4.256308310.55 4.45523569

0.525 4.700430680.5 5.00266018

0.475 5.373900240.45 5.83549729

0.425 6.417681160.4 7.16726389

0.375 8.16003290.35 9.5271897

0.325 11.5257230.3 14.6809142

0.275 20.38993530.25 33.769404

0.225 100.99113

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.10

20

40

60

80

100

120x1

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.10

20

40

60

80

100

120x1

X1 y11 1

0.975 0.919615670.95 0.84820824

0.925 0.784579890.9 0.72772113

0.875 0.676775280.85 0.63101359

0.825 0.589812950.8 0.55263901

0.775 0.519031570.75 0.48859235

0.725 0.460974880.7 0.43588003

0.675 0.413042760.65 0.39223404

0.625 0.373248180.6 0.35590792

0.575 0.340054610.55 0.32554498

0.525 0.312253540.5 0.30010635

0.475 0.288915410.45 0.278635

0.425 0.269180480.4 0.26047674

0.375 0.252451470.35 0.24503725

0.325 0.238237550.3 0.23188435

0.275 0.22595620.25 0.2203874

0.225 0.215098140.2 0.20999493

0.175 0.204950330.15 0.19977023

0.125 0.194135380.1 0.18745081

0.075 0.178425630.05 0.16370499

0.025 0.131357630 0

0 0.2 0.4 0.6 0.8 1 1.20

0.2

0.4

0.6

0.8

1

1.2

f(x) = 0.7492309891xR = 0.9605866905

X1

0 0.2 0.4 0.6 0.8 1 1.20

0.2

0.4

0.6

0.8

1

1.2

f(x) = 0.7492309891xR = 0.9605866905

X1

x1 y1 T (k) T Y10 1 369.75 96.6

0.013 0.984 369.4 96.25 2.1740.038 0.905 367.84 94.69 3.0560.083 0.854 366.07 92.92 2.9890.016 0.794 363.8 90.65 2.760.226 0.739 362.46 89.31 2.530.283 0.663 361.63 88.48 2.3370.356 0.643 360.82 87.67 2.1360.426 0.632 360.47 87.32 1.939

0.5 0.627 360.33 87.18 1.750.583 0.619 360.28 87.13 1.5640.648 0.613 360.27 87.12 1.440.708 0.608 360.32 87.17 1.3380.763 0.603 360.44 87.29 1.2520.817 0.595 360.62 87.47 1.1710.853 0.585 360.78 87.63 1.1240.883 0.572 360.93 87.78 1.090.911 0.55 361.12 87.97 1.0620.926 0.522 361.43 88.28 1.0410.945 0.487 361.77 88.62 1.0240.957 0.437 362.41 89.26 1.0180.967 0.39 363.3 90.15 1.0030.978 0.317 365.06 91.91 1.0040.985 0.194 366.87 93.72 10.991 0.097 368.71 95.56 0.9990.996 0.0683 370.23 97.08 0.9960.999 0.025 371.95 98.8 1.015

1 0 372.78 99.63

Y2 PV PROPANOLPV AGUA(BAR)1 3.54965 1.00677271 0.9614989711

0.994 1.00055 3.416743 0.98438397 0.94106383571.003 1.002233 3.286855 0.96528867 0.92362917031.006 1.005094 3.160771 0.94896841 0.90872388611.018 1.009181 3.039027 0.9349756 0.89594093311.041 1.014546 2.92195 0.922954 0.88495619831.072 1.021246 2.809708 0.91261127 0.8755035691.124 1.029348 2.702357 0.90370641 0.86736356621.192 1.038926 2.599864 0.89604011 0.86035460061.295 1.050069 2.50214 0.88944452 0.8543236816

1.48 1.062877 2.409048 0.88378147 0.84914481341.701 1.077469 2.320429 0.8789334 0.84471075721.997 1.093983 2.236101 0.87479781 0.8409279865

2.4 1.112583 2.155874 0.87129268 0.83772162353.047 1.133456 2.079554 0.86834215 0.8350223963

3.72 1.156826 2.006948 0.86588677 0.83277602554.574 1.182956 1.937864 0.86386958 0.83093044735.841 1.212157 1.872116 0.8622434 0.82944255256.844 1.244799 1.809527 0.86096916 0.82827662988.812 1.281324 1.749924 0.86001121 0.8274000983

10.369 1.322269 1.693148 0.85928602 0.826736527812.265 1.368269 1.639038 0.85888213 0.826366948414.126 1.42012 1.587452 0.85871337 0.826212527815.232 1.478795 1.538254 0.85876008 0.826255267416.756 1.545509 1.491316 0.85900268 0.826477259823.145 1.621795 1.446519 0.85942771 0.826866180724.348 1.709615 1.403751 0.86002478 0.8274125175

1.811534 1.362912 0.86070358 0.82803362771.930901 1.323908 0.861585 0.82884012362.072277 1.286654 0.86261804 0.82978534

2.24195 1.251079 0.86380305 0.83086957142.448852 1.217121 0.86515704 0.83210838792.706091 1.184734 0.86670627 0.83352578353.033681 1.153891 0.86850599 0.8351722883

3.46369 1.124596 0.87066045 0.83714325784.050744 1.096896 0.87338133 0.83963227244.895525 1.070919 0.87711288 0.8430455961

6.20449 1.046951 0.8829215 0.84835831678.470845 1.025613 0.89382284 0.858327251813.19481 1.008421 0.92133486 0.883476522627.81242 1 1.05424955 1.0048115864

0 0.2 0.4 0.6 0.8 1 1.280

85

90

95

100

105


1-Propanol 4.99991 1512.94 205.807Agua 5.11564 1687.537 230.17

FORMULA.

C3H8OH2O

Ref:POLING, BRUCE; PRAUSNITZ, JOHN & O'CONNELL, JOHN."ThePropertiesofGasesandLiquids".5thedition.McGrawHill.NewYork.2001

log10Pvap=A-[B/(TC+C)]bar

0 0.2 0.4 0.6 0.8 1 1.280

85

90

95

100

105

POLING, BRUCE; PRAUSNITZ, JOHN & O'CONNELL, JOHN."ThePropertiesofGasesandLiquids".5thedition.McGrawHill.NewYork.2001

x1 y1 T (k) T Y1 Y20 1 369.75 96.6

0.013 0.984 369.4 96.25 2.174 0.9940.038 0.905 367.84 94.69 3.056 1.0030.083 0.854 366.07 92.92 2.989 1.0060.016 0.794 363.8 90.65 2.76 1.0180.226 0.739 362.46 89.31 2.53 1.0410.283 0.663 361.63 88.48 2.337 1.0720.356 0.643 360.82 87.67 2.136 1.1240.426 0.632 360.47 87.32 1.939 1.192

0.5 0.627 360.33 87.18 1.75 1.2950.583 0.619 360.28 87.13 1.564 1.480.648 0.613 360.27 87.12 1.44 1.7010.708 0.608 360.32 87.17 1.338 1.9970.763 0.603 360.44 87.29 1.252 2.40.817 0.595 360.62 87.47 1.171 3.0470.853 0.585 360.78 87.63 1.124 3.720.883 0.572 360.93 87.78 1.09 4.5740.911 0.55 361.12 87.97 1.062 5.8410.926 0.522 361.43 88.28 1.041 6.8440.945 0.487 361.77 88.62 1.024 8.8120.957 0.437 362.41 89.26 1.018 10.3690.967 0.39 363.3 90.15 1.003 12.2650.978 0.317 365.06 91.91 1.004 14.1260.985 0.194 366.87 93.72 1 15.2320.991 0.097 368.71 95.56 0.999 16.7560.996 0.0683 370.23 97.08 0.996 23.1450.999 0.025 371.95 98.8 1.015 24.348

1 0 372.78 99.63

formulas100.2383 96.77947

95.1773593 96.16622794.281216 93.4570471

92.7806787 91.989632295.0674645 90.546085188.9726252 89.491430887.8619479 88.456881686.7784927 88.266166486.0971292 88.17575485.7574725 88.138054785.8419851 88.082152386.2518046 88.043792786.8980062 88.014161987.7162923 87.986654588.7299536 87.94705989.5214636 87.905208690.2517825 87.863500390.9914242 87.825615991.4107009 87.836851891.9648603 87.94453492.3281439 88.278846292.6387388 88.78670292.9886448 89.9475013

93.215813 92.92713893.4133149 96.183156793.5798644 97.299735293.6806514 99.1167212

96.77947 100.2383

0 0.2 0.4 0.6 0.8 1 1.275

80

85

90

95

100

105

0 0.2 0.4 0.6 0.8 1 1.275

80

85

90

95

100

105

Y(P) TEMPERATURA Y (P) C

0 100.0177222222 20.863380.025 92.0951111111 10.67599

0.05 89.2641666667 7.0098590.075 88.1076111111 5.121812

0.1 87.6512222222 3.9787190.125 87.5083333333 3.219527

0.15 87.5022777778 2.6842130.175 87.5475 2.290637

0.2 87.6028888889 1.9921920.225 87.6496666667 1.760444

0.25 87.6811111111 1.5770750.275 87.6967222222 1.429775

0.3 87.6991111111 1.309990.325 87.6898333333 1.211485

0.35 87.6798888889 1.1300920.375 87.6702777778 1.062309

0.4 87.6656666667 1.0056260.425 87.6705 0.9581233

0.45 87.6887777778 0.91831080.475 87.7241666667 0.8850231

0.5 87.7800555556 0.85734180.525 87.8596111111 0.8345396

0.55 87.9656111111 0.81603890.575 88.0994444444 0.8013353

0.6 88.2664444444 0.79015490.625 88.4676666667 0.7821726

0.65 88.7056666667 0.77717050.675 88.9826666667 0.7749859

0.7 89.3010555556 0.77550440.725 89.6631111111 0.7786534

0.75 90.0712222222 0.78439850.775 90.5276111111 0.7927399

0.8 91.0346666667 0.80371050.825 91.5948333333 0.8173742

0.85 92.2103888889 0.8338250.875 92.8837222222 0.8531866

0.9 93.6172222222 0.87561160.925 94.4131111111 0.9012818

0.95 95.2732777778 0.9303971

0.975 96.2001111111 0.96321241 97.1956666667 1

Y (W) GAMMA 1 GAMMA 2 y1 y2 x1

0.9999959 18.77578 1 0 1 00.7519233 12.98564 1.004428 0.2668593 0.7331407 0.0250.6836967 9.534378 1.016409 0.3504833 0.6495167 0.050.6657999 7.296444 1.034593 0.3841326 0.6158674 0.0750.6690297 5.773106 1.058023 0.3978717 0.6021283 0.10.6829221 4.698527 1.085956 0.4024421 0.5975579 0.1250.7027829 3.918262 1.117801 0.4026337 0.5973663 0.150.7262254 3.337639 1.153072 0.4008635 0.5991365 0.175

0.751949 2.896305 1.191371 0.3984403 0.6015597 0.20.7792232 2.55456 1.232361 0.3961017 0.6038983 0.2250.8076391 2.285577 1.275756 0.3942703 0.6057297 0.250.8369796 2.070801 1.321308 0.3931895 0.6068105 0.2750.8671454 1.897126 1.368803 0.3929979 0.6070021 0.30.8980196 1.755127 1.418044 0.3938048 0.6061952 0.325

0.929842 1.637869 1.468859 0.3955749 0.6044251 0.350.9625456 1.540225 1.521083 0.3983874 0.6016126 0.3750.9962134 1.458311 1.574564 0.4022586 0.5977414 0.4

1.030946 1.389154 1.629157 0.4072034 0.5927966 0.4251.066856 1.330451 1.68472 0.4132385 0.5867615 0.451.104071 1.280396 1.741113 0.4203861 0.5796139 0.4751.142726 1.237558 1.798197 0.4286753 0.5713247 0.51.182967 1.200792 1.855834 0.4381439 0.5618561 0.5251.224953 1.169171 1.913881 0.4488394 0.5511606 0.551.268783 1.141943 1.972193 0.460768 0.539232 0.5751.314769 1.118485 2.030617 0.4740931 0.5259069 0.61.363047 1.098282 2.088996 0.4888581 0.5111419 0.6251.413827 1.080906 2.147167 0.505161 0.494839 0.651.467338 1.065995 2.204958 0.5231157 0.4768843 0.6751.523824 1.053244 2.262189 0.5428532 0.4571468 0.7

1.58355 1.04239 2.318671 0.5645238 0.4354762 0.7251.646804 1.033208 2.374204 0.5882988 0.4117012 0.751.713895 1.025504 2.42858 0.6143733 0.3856267 0.7751.785157 1.019108 2.481579 0.6429682 0.3570318 0.81.860949 1.01387 2.532971 0.6743334 0.3256666 0.8251.941657 1.009658 2.582518 0.7087508 0.2912492 0.852.027693 1.006353 2.629972 0.7465378 0.2534622 0.8752.119495 1.003848 2.675077 0.7880499 0.2119501 0.92.217526 1.002047 2.717573 0.8336851 0.1663149 0.9252.322247 1.000859 2.757198 0.8839045 0.1160955 0.95

2.434195 1.000202 2.793683 0.9391519 0.0608481 0.9752.553896 1 2.826763 1 0 1

x2

1 APLICACIN 1/(y1-x1)0.975 1

0.95 1 0.02434931 1.578041990.925 1 0.04069887 1.69262046

0.9 1 0.05496688 1.757377510.875 1 0.06632798 1.79236492

0.85 1 0.07463198 1.809028460.825 1 0.07996608 1.81413991

0.8 1 0.08246936 1.811761590.775 1 0.08225691 1.80432721

0.75 1 0.07939227 1.793274540.725 1 0.07387913 1.77942402

0.7 1 0.06566106 1.763216280.675 1 0.05467773 1.745141

0.65 1 0.04062775 1.724607740.625 1 0.02334709 1.70199556

0.6 1 0.002534 1.67725180.575 1 -0.02218655 1.65031207

0.55 1 -0.05127249 1.621123890.525 1 -0.0852839 1.58964568

0.5 1 -0.12489958 1.555872950.475 1 -0.17094871 1.51983306

0.45 1 -0.22445151 1.481584640.425 1 -0.28661133 1.44137288

0.4 1 -0.35911518 1.39905340.375 1 -0.44391597 1.35492726

0.35 1 -0.5435855 1.309196980.325 1 -0.66148704 1.26208764

0.3 1 -0.80209788 1.21385150.275 1 -0.97151969 1.16475453

0.25 1 -1.17828958 1.115070850.225 1 -1.43472714 1.06508182

0.2 1 -1.75930072 1.015066630.175 1 -2.18101601 0.96529848

0.15 0.999999 -2.7481972 0.916038650.125 0.999999 -3.54780088 0.86753368

0.1 0.999999 -4.75370548 0.820011560.075 0.999999 -6.77157968 0.77367883

0.05 0.999999 -10.8182691 0.72873178

alfa

0 0.2 0.4 0.6 0.8 1 1.280

85

90

95

100

105

0.025 0.999999 -22.9782762 0.685309370 0.999999 #DIV/0! 0.64354371

0

0 0.2 0.4 0.6 0.8 1 1.280

85

90

95

100

105

DATOS ASPENINFORMACIONANTOINECOMPOSICIONDATOSGRAFICOSMETODO EXP.AJUSTEWILLSON

Octavio Manazano Mora

Documents

Transcript of Octavio Manazano Mora